| | Production of carboxylic acids by controlling the active form of iridium catalyst in response to infrared absorption ... |
 | | By monitoring the infrared absorption spectra of reacting solutions and following the magnitude of the 2098 cm.sup.-.sup.1 band the operating conditions are adjusted so that this band is present in 50 percent or more concentration relative to the infrared absorption spectral bands of the other iridium species in solution. |
 | | This disadvantage has now been found to be overcome by monitoring the infrared absorption spectra of the reaction solution and employing feedback control of the operating conditions so as to have a high proportion of the expensive iridium in the preferred form (i.e., having the major band at 2098 cm.sup..sup.-1). |
 | | Infrared absorption spectra of the reaction solution can be carried out on samples removed from the reactor and placed in standard liquid cells at ambient conditions or, preferably, through the use of an in situ high temperature-high pressure spectral cell as described in THE REVIEW OF SCIENTIFIC INSTRUMENTS, 43, No. 7, July 1972, pg. |
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