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| | Process for the manufacture of anthraquinone compounds - Patent 4086252 |
 | | A process as claimed in claim 1 wherein the alkenyl carboxylic acid is added to the sulphuric acid containing the aminoanthraquinone and the boric acid, metaboric acid or boric oxide, the reaction mixture is stirred at a temperature between 20.degree. |
 | | The anthraquinone compounds containing primary amino groups used as starting materials in the process of the invention can additionally contain further substituents other than sulphonic acid groups, for example hydroxy, chlorine, bromine, methyl, methoxy,.beta.-methoxyethoxy, cyano, carboximide, nitro, aryl, arylamino, alkylamino, cycloalkylamino, dialkylamino, alkylthio and arylthio. |
 | | As specific examples of such anthraquinone compounds there may be mentioned 1-aminoanthraquinone, 1:4-, 1:5- or 1:8-diaminoanthraquinone, 1:4:5-triaminoanthraquinone, 1:4:5:8-tetraaminoanthraquinone, 1-amino-4-hydroxyanthraquinone, 1:5-diamino 4:8-dihydroxyanthraquinone, 1:8-diamino-4:5-dihydroxyanthraquinone, 1-amino-2-(methyl- or methoxy)-anthraquinone, 1-amino-2-(bromo-, cyano-, nitro- or methyl-)-4-hydroxyanthraquinone, 1:4-diamino-2-(bromo-, cyano-, methylthio-, n-butylthio-, phenylthio, or methoxy-)anthraquinone, 1-amino-4-anilinoanthraquinone, 1:4-diamino-6:7-dichloroanthraquinone, 1:5-diamino-4-hydroxy-8-anilinoanthraquinone, 1:5-diamino-4:8-dihydroxy-2-(4'-hydroxyphenyl)anthraquinone, 1-amino-4,5-dihydroxy-8-nitroanthraquinone, and 1-amino-4:8-dihydroxy-5-nitroanthraquinone. |
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