| | Chemical Approaches to Artificial Photosynthesis. 2 (Site not responding. Last check: 2007-11-02) |
 | | In artificial photosynthesis, the goal is to harness the energy of the sun to drive high-energy small-molecule reactions such as water splitting, eq 2, or CO reduction, eq 3. |
 | | Possible application of this approach to artificial photosynthesis and the fuel-forming reaction in eq 3 is illustrated in Figure 3, which highlights the electrode as the initial electron acceptor rather than a molecular unit in a molecular assembly. |
 | | The greatest chemical challenge in the modular approach to artificial photosynthesis is identifying catalysts that have the ability to carry out the necessary multiple electron transformations at energies and rates consistent with the solar irradiance. |
| pubs.acs.org /cgi-bin/sample.cgi/inocaj/2005/44/i20/html/ic050904r.html (9642 words) |