| | Interaction of Tantalum with Diatomic and Atomic Oxygen at Low Pressures (Site not responding. Last check: 2007-10-23) |
 | | Two sections can be distinguished in the curves: the first corresponds to dissolution of oxygen in tantalum, and the second -- to the growth of oxide scale. |
 | | As the experiments demonstrated, first-order kinetics are observed at the stage of oxygen dissolution in metal, besides, atoms and molecules are absorbed independently, i.e. |
 | | A kinetic model is proposed explaining the results of the experiments at various oxygen pressures and dissociation efficiences, which is based on assumption that tantalum oxidation rate at the stage of oxide scale growth is determined by the reaction of oxygen atoms chemisorbed on Ta surface in accordance with Langmuir-Hinshelwood mechanism (see Ref.1 for details). |
| www.chem.utoronto.ca /~sraspopo/ext_abstract_Ta.html (587 words) |