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Topic: Bipyridine


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  Bipyridine - Wikipedia, the free encyclopedia
Bipyridine is one of the simplest polypyridine compounds.
Bipyridine is a white solid, soluble in organic solvents, and slightly soluble in water.
There are six isomers of bipyridine; among them, a well-known structure is 2,2'-bipyridine.
en.wikipedia.org /wiki/Bipyridine   (207 words)

  
 Bipyridine Chemistry
Despite their apparent simplicity, methyl bipyridines and other unsymmetrical bpys have long been difficult to make efficiently.
A new and improved route to halomethyl functionalized bipyridine ligands was devised.
Using (trimethylsilyl)methyl bipyridines as the starting point, an efficient synthesis of hydroxymethyl bipyridines was developed.
faculty.virginia.edu /fraserlab/BpyChemistry.htm   (426 words)

  
 Synthesis and complexation characteristics of phenanthroline and bipyridine diols   (Site not responding. Last check: 2007-10-14)
The bipyridine bridge moiety is almost flat and the hydroxy groups are directed towards the zinc ion.
In the first residue (left)  one copper ion is symmetrically bond to the bipyridine nitrogens, an acetate oxygen and the hydroxylates of the ligand to form square pyramidal surroundings (Cu(1)…N(1) 1.954 Å; Cu(1)…N(2) 2.000 Å; Cu(1)…O(3) 2.342 Å; Cu(1)…O(1) 1.913 Å; Cu(1)…O(2) 1.913 Å).
The bipyridine backbone is nearly flat, a torsion angle of -4.2° being observed.
www.arkat-usa.org /ark/journal/2004/I02_Zwanenburg/BZ-951E/951E.asp   (5591 words)

  
 Riitta Laitinen. New heterodonor phosphine and bipyridine ligands. ISBN 951-42-5229-2
Academic Dissertation to be presented with the assent of the Faculty of Science, University of Oulu, for public discussion in Raahensali (Auditorium L 10), on May 28th, 1999, at 12 noon.
Twenty-seven phosphine and six bipyridine ligands were synthesised and characterized.
The phosphine ligands contain thiomethylphenyl, methoxyphenyl, dimethylaminophenyl, pyridyl, naphthyl and anthracenyl groups, and the bipyridine ligands thiomorpholine and piperidine groups.
herkules.oulu.fi /isbn9514252292   (186 words)

  
 Publications
"Bipyridines" Fraser, C. L.; Smith, A. Comprehensive Coordination Chemistry II; Meyer, T. J.; McCleverty, J. A., Eds; Elsevier Ltd.: Oxford, UK, 2004; Vol.
Metal-Centered Heteroarm Polymers: Chelation of Linear Polystyrene-b-Polycaprolactone Subunits with a Bipyridine Donor at the Block Junction" Smith, A. Fraser, C. Macromolecules 2002, 35, 594-596.
"Synthesis of Halomethyl and Other Bipyridine Derivatives by Reaction of 4,4'-Bis[(trimethylsilyl)methyl]-2,2'-bipyridine with Electrophiles in the Presence of Fluoride Ion" Fraser, C. L.; Anastasi, N. R.; Lamba, J. Org.
faculty.virginia.edu /fraserlab/publications.htm   (1584 words)

  
 RuTrisBpy
The filled subshell has spherical symmetry and any incoming ligands will face electrostatic repulsion from the electrons in the filled orbitals regardless of which direction they approach the complex from.
Each bipyridine bonds twice to the metal center through the donation of the lone pair electrons on both nitrogen atoms.
If one of the metal-nitrogen bonds is broken, the other metal-nitrogen bond will hold the ligand in place long enough for the broken bond to re-form.
antoine.frostburg.edu /chem/simon/chm411/lab/Rubpy3.htm   (1884 words)

  
 kemian laitos - joensuun yliopisto
Homanen P, Haukka M, Pakkanen TA, Pursiainen J & Laitinen RH: Ruthenium(II) Bipyridine Complexes: Synthesis and Characterization of Ru(bpy)(CO)2(SCN)2, Ru(dmbpy)(CO)2Cl2 and Ru(dmbpy)(CO)2(NCS)H (bpy=2,2'-bipyridine, dmbpy=6,6'-dimethyl -2,2'-bipyridine) Organometallics 15 (1996) 4081-4084.
Homanen P, Haukka M, Ahlgren M, Pakkanen TA, Baxter PNW, Benfield RE and Connor JA: Ruthenium bipyridine complexes: Synthesis and characterization of Ru(tmbpy)(CO)2Cl2, Ru(dmbpy)(CO)2Cl2, (RU(dmbpy)(CO)2Cl2).
Kinnunen T-JJ, Haukka M, Pakkanen TT, Pakkanen TA: Four-coordinated bipyridine complexes of nickel for ethene polymerization ­ the role of ligand structure.
www.chem.joensuu.fi /department/publications/publica96-00.html   (4436 words)

  
 First-principles calculation of the conductance of a single 4,4 bipyridine molecule   (Site not responding. Last check: 2007-10-14)
First-principles calculation of the conductance of a single 4,4 bipyridine molecule
The conductance of a single 4,4 bipyridine (44BPD) molecule connected to two gold electrodes is calculated using a density functional theory based Green function method.
The atomic geometry of such a molecular junction is constructed from the optimized structure of a gold trimer–44BPD–gold trimer complex.
stacks.iop.org /0957-4484/16/239   (285 words)

  
 University of Virginia Department of Chemistry
First, we develop efficient approaches to functionalized ligands and their metal complexes.
Initially, our efforts concentrated on bipyridine systems; however, more recently, the polymeric metal complex design has also been expanded to include beta-diketonates and other ligand systems as well.
Next, we test the compatibility of these reagents as initiators with various living polymerizations.
www.virginia.edu /chem/people/faculty/fraser   (578 words)

  
 Alexander von Zelewsky   (Site not responding. Last check: 2007-10-14)
Diastereoselective synthesis of coordination compounds: a chiral tripodal ligand based on bipyridine units and its ruthenium(II) and iron(II) complexes.
Platinum(II) com pounds with enantiomerically pure bis(pinene)-fused bipyridine ligands - diimine-dichloro compl exes and their substitution reactions.
Stereoselective synthesis of hexac oordinated mononuclear cyclometalated rhodium(III) complexes - transfer of chirality from the m etal center to the ligand.
www-chem.unifr.ch /avz/zelewsky.html   (1340 words)

  
 publications   (Site not responding. Last check: 2007-10-14)
Bipyridine building blocks for self-organizating systems: first complete NMR-spectroscopic investigation of 6,6'-disubstituted 2,2'-bipyridines obtained via n-oxidation route and related reactions
Synthesis of functionalized polymers with bipyridine and terpyridine segments using metallo-supramolecular initiators
New soluble functional polymers by free-radical copolymerization of methacrylates and bipyridine ruthenium complexes
www.schubert-group.de /publications_1.htm   (3902 words)

  
 for Marcia   (Site not responding. Last check: 2007-10-14)
and properties of macrocyclic bipyridine zirconocene complex); Coupling reaction; Macrocyclization (prepn.
and properties of macrocyclic bipyridine zirconocene complex); 310408-05-0P Role: PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PREP (Preparation) (prepn.
FIELD Supplementary Terms:zirconocene coupling macrocyclic compd prepn; mol structure bipyridine zirconocene complex macrocyclic; crystal structure bipyridine zirconocene complex macrocyclic; diyne prepn macrocyclization zirconocene Rosenthal; macrocyclization zirconocene coupling
home.wlu.edu /~blackmerh/scilib/marcia9.html   (11784 words)

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