Factbites
 Where results make sense
About us   |   Why use us?   |   Reviews   |   PR   |   Contact us  

Topic: Boltzmann factor


Related Topics

  
  Theoretical Principles of Plasma Physics and Atomic Physics
Boltzmann Equation: As a generalized form of the Continuity Equation, the Boltzmann equation gives an exact description for the density of a plasma constituent both in real and velocity space.
Examples for a detailed balance equation are the Boltzmann Equation and the equation for the atomic Level Population (in contrast, for both of these cases LTE -models with their given energy distribution will generally yield invalid results).
Oscillator Strength: The oscillator strength is the factor by which the scattering cross for a classical damped oscillator has to be multiplied in order to yield the quantum mechanical Resonance Scattering cross section, i.e.
www.plasmaphysics.org.uk   (7930 words)

  
  Factor
Boltzmann factor In temperature T being in a state with energy E: is partition function.
Factor A factor can be: a person acting as a mercantile agent a number that is a divisor of another number in mathematic...
Factor V Leiden Factor V Leiden is a hypercoagulability disorder in which, Factor V, one of the hereditary hypercoagulab...
www.brainyencyclopedia.com /topics/factor.html   (996 words)

  
 [No title]   (Site not responding. Last check: 2007-10-29)
Boltzmann held that the second law of thermodynamics - formulated in 1850 by Rudolph Clausius* and Kelvin* and concerns energy exchange - should be considered from this standpoint, and could be explained by applying the laws of mechanics and the theory of probability to the motions of the atoms.
Although Boltzmann received important recognition for his work in 1899 when he was made a fellow of the Royal Society of London, the following year, largely owing to his dislike of working alongside Mach, he chose to move to the University of Leipzig.
On his return to Vienna, Boltzmann continued to defend his belief in atomic structure and in a 1905 publication 'Populare Schriften' he attempted to explain how, while the physical world could be described macroscopically by differential equations, the underlying atomic structure remained unrepresented.
www.cyburkespace.info /content/nodes/Boltzmann.txt   (732 words)

  
 Encyclopedia: Boltzmann factor
In physics, the Boltzmann factor is a weighting factor determining the relative probability of a system in thermodynamic equilibrium at a temperature T being in a state with energy E: Wikibooks Wikiversity has more about this subject: School of Physics sci.
The Boltzmann constant (k or kB) is the physical constant relating temperature to energy.
In a plasma, the Boltzmann relation connects the electron density ne to the plasma potential φpl as follows: ne = n0 exp(eφpl/kBTe) The reference for the potential potential is taken to be a position where the electron density is n0.
www.nationmaster.com /encyclopedia/Boltzmann-factor   (439 words)

  
 boltzmann   (Site not responding. Last check: 2007-10-29)
Boltzmann's Law states that at equilibrium the probability of finding an energy H in some molecular "degree of freedom", such as motion along the x axis or vibration of a particular C-H bond, is proportional to e
Boltzmann was certainly not disturbed by this indistinguishability, because he didn't really think that energy came in little bits anyway.
S contributes a factor to the equilibrium (or rate) constant that is independent of temperature.
classes.yale.edu /chem125a/125/kinetics/Boltzmann/boltzmann.htm   (1355 words)

  
 Boltzmann factor Definition / Boltzmann factor Research   (Site not responding. Last check: 2007-10-29)
In physics, the Boltzmann factor is a weighting factor determining the relative probability of a system in thermodynamic equilibriumIn thermodynamics, a thermodynamic system is in thermodynamic equilibrium if its energy distribution equals a Maxwell-Boltzmann-distribution.
To normalize the Boltzmann factor into a probability, one simply divides it by the sum Z of the Boltzmann factors of all possible states of a system, which sum is named the partition function.
Boltzmann factor is the small probability of repeatedly gaining extra energy at random from a large number of other particles.
www.elresearch.com /Boltzmann_factor   (173 words)

  
 Boltzmann's Factor
This factor can be used to introduce temperature into a wide variety of physical problems, and is often taken as a starting point.
Nevertheless, Ludwig Boltzmann (1844-1906) and Josiah Willard Gibbs (1839-1903) came very close to a reasonable theory, which was completely clarified with the appearance of quantum mechanics.
The Boltzmann factor is perhaps the most useful result of statistical mechanics, applicable to many problems, and which can even be carried over to problems expressed in classical mechanics, though it is fundamentally a counting of states.
www.du.edu /~jcalvert/phys/boltz.htm   (5653 words)

  
 Statistical mechanics   (Site not responding. Last check: 2007-10-29)
The entropy of a macroscopic state is proportional to the logarithm of the number of microscopic states corresponding to it.
The partition function is a measure of the number of states accessible to the system at a given temperature.
See Derivation of the partition function for a proof of Boltzmann's factor and the form of the partition function from first principles.
www.1-free-software.com /en/wikipedia/s/st/statistical_mechanics_1.html   (906 words)

  
 Correlation between rate of enzyme-substrate diffusional encounter and average Boltzmann factor around active site   (Site not responding. Last check: 2007-10-29)
The utility of the average Boltzmann factor around the active site of an enzyme as the predictor of the electrostatic enhancement of the substrate binding rate is tested on a set of data on wild-type acetylcholinesterase and 18 charge mutants recently obtained by Brownian dynamics simulations.
A good correlation between the average Boltzmann factors and the substrate binding rate constants is found.
The effects of single charge mutations on both the Boltzmann factor and the substrate binding rate constant are modest, i.e., < 5 fold increase or decrease.
adrik.bchs.uh.edu /abstracts/355Biop1998.htm   (177 words)

  
 Definition of Factor
If the Q factor of a [[laser]]'s cavity is abruptly changed, the...
5:...mply divides it by the sum ''Z'' of the Boltzmann factors of all possible states of a system, which sum is...
Ratnoff later found that the Hageman factor deficiency is [[autosomal recessive]] disorder, w...
www.wordiq.com /search/Factor.html   (717 words)

  
 Dictionary of Meaning www.mauspfeil.net
In physics, the '''Boltzmann factor''' is a weighting factor determining the relative probability of a system in thermodynamic equilibrium at a temperature ''T'' being in a state with energy ''E'': :
To normalize the Boltzmann factor into a probability, one simply divides it by the sum ''Z'' of the Boltzmann factors of all possible states of a system, which sum is called the partition function (statistical mechanics) partition function.
From the Boltzmann factor, one can then derive the Maxwell-Boltzmann statistics, Bose-Einstein statistics, and Fermi-Dirac statistics that govern classical particles as well as quantum mechanics quantum mechanical bosons, and fermions, respectively.
www.mauspfeil.net /Boltzmann_factor.html   (203 words)

  
 sdabf - Averaging Boltzmann factor within specified reaction distance   (Site not responding. Last check: 2007-10-29)
The average Boltzmann factor within a reaction distance is computed as an average over all points not leading to overlaps and satisfying the reaction conditions within the specified distance.
The orientation averaged Boltmann factor on the grid is computed as an average over all random orientations of the protein, while its center is kept fixed.
Here the rate enhancements are shown, which were obtained by computing Boltzmann factors (marked bf) for the encounter complexes defined by 2 or 3 contacts at the distance specified on the x-axis; there are 2 curves for each Boltzmann factor, which correspond to 2 different ways of sampling the Boltzmann factors.
www.embl-heidelberg.de /~gabdoull/sda/sdabf.html   (1373 words)

  
 Where does the Boltzmann factor come from?   (Site not responding. Last check: 2007-10-29)
This is a factor that shows up in situations where the temperature, T, is given; it is (proportional to) the probability that the system is in a state with energy E, where k is Boltzmann's constant (which you may have seen in the ideal gas law in a chemistry class).
The Boltzmann factor is the basis of a huge amount of thermodynamic and statistical physics, both classical and quantum.
The other factor is just a constant, which will be the same for all of the states; we can ignore that because we typically take care of the overall normalization of probabilities by dividing expectation values by the integral of e^(-E/kT), the famous partition function.
www.theworld.com /~mmcirvin/boltzmann.html   (2622 words)

  
 Appendix B: Reaction rate
Normalizing the Boltzmann factor with the concentration gives the correct result for the transition state theory rate for the second order rate coefficient.
In the second place, does the free energy in the exponential term of equation 3.9 include a correction for the fact that not in all occasions that the system reaches the transition state, it actually crosses the barrier to end up in the product well.
Instead, the computed Boltzmann factor (equation 3.10) is an ensemble average that only gives the (transition state theory) upper limit of the rate constant
www.cmm.upenn.edu /~ensing/thesis/node28.html   (534 words)

  
 Maxwell-Boltzmann Distribution Law   (Site not responding. Last check: 2007-10-29)
T is the absolute temperature, N is number of molecules, m is mass of a molecule, v is the velocity of a molecule, k is the Boltzmann constant 13.805 x 10
By analysis of the transfer of momentum during collisions between molecules, Maxwell determined that the volume element must be multiplied by the Boltzmann factor exp(-
Below is a plot of the probability distribution of molecules as a function of velocity at three temperatures.
www.tannerm.com /maxwell_boltzmann.htm   (143 words)

  
 boltzmann   (Site not responding. Last check: 2007-10-29)
It should not surprise you to learn that in 1877 when Boltzmann, who was good at math, found the limiting case for many atoms and infinitesimal energy packets, the distribution turned out to be exactly his decaying exponential (e
Furthermore, you can appreciate the reason that concentration of energy in a single atom is unlikely - because it limits the number of permutations of the rest of the energy.
H /RT That is, after all this rigamarole 1.377 cal/mole/K just came out to mean a factor of 2 in the equilibrium constant.
ursula.chem.yale.edu /~chem125/125/kinetics/Boltzmann/boltzmann.htm   (1089 words)

  
 Molecular Simulation – MC and MD
If the energy of the new configuration is higher than the energy of its predecessor, then the Boltzmann factor of the energy difference is calculated: exp (-DU/kT).
The Boltzmann factor is compared with a random number between 0 and 1.
If the random number is lower than the Boltzmann factor, the new configuration is accepted and the configuration is included.
www.chm.bris.ac.uk /pt/ajm/mmhtm/MM_L4p6.htm   (610 words)

  
 Extracting physical quantities
Thus, it is not worth while to integrate over the 2,057,152 variables because at most values of these variables the contribution of the Boltzmann factor to the partition function is negligible.
The dependence on the Wilson loop on size was measured in lattice QCD in a large number of simulations and an excellent agreement was found with the area law.
The clinching factor of showing that continuum QCD confines is however the result of the investigation of the continuum limit of the area law.
www.physics.uc.edu /suranyi/conf-lectures/node18.html   (1768 words)

  
 VELOCITY DISTRIBUTION   (Site not responding. Last check: 2007-10-29)
The first part of this Section is devoted to the introduction of the Boltzmann factor.
The question can be posed of finding the probability that a particle has an energy E when it is at equilibrium with a system at temperature T. This probability is found to be inversely proportional to the exponential of the energy.
Let us see how the Boltzmann factor can be obtained in the case of a system of particles in a gravitational field.
colos1.fri.uni-lj.si /~colos/COLOS/TUTORIALS/JAVA/THERMODYNAMICS/THERMO_UK/HTML/Vel_Distri.html   (991 words)

  
 phd-ch6
One approach to evaluating this integral and finding the average is to pick configurations in phase space randomly from a uniform distribution of all configurations, weight the property by the Boltzmann factor, and sum all the weighted terms.
However, as the Boltzmann factor is small for most configurations - corresponding to molecular overlaps in the liquid - the sampling is inefficient.
Explaining how points are picked randomly according to the Boltzmann distribution is equivalent to explaining how given one configuration of a liquid, it is possible to generate another configuration such that resulting sequence of configurations is distributed according to the Boltzmann distribution.
bioinfo.mbb.yale.edu /geometry/mbg-phd/phd-ch6.html   (908 words)

  
 Preclass QUIZ Spring 2004   (Site not responding. Last check: 2007-10-29)
The Boltzmann factor takes into account the probability of thermal energy being able to excite a state.
The Boltzmann factor is supremely important because it indicates how the energy affects the population of states in a system.
The Maxwell-Boltzmann distribution function, Manchester --essentially another name for the Boltzmann factor, should be appropriate for all situations for which the quantum nature of matter is not important.
www.physics.ohio-state.edu /~aubrecht/quiz/0605.html   (220 words)

  
 Configurational biased Monte Carlo, Metropolis importance sampling, weighting factor - Science-Park.info   (Site not responding. Last check: 2007-10-29)
A weighting factor has to be calculated in order to take into account for the bias.
for a particlular selected bead, where i refers to a bead label (0,1,2,...,N) and B is the sum of the total Boltzmann factor for all trial beads for Bead i.
In order to decide whether to accept the newly grown chain or not, the ratio of weighting factors for the new chain over the old chain, W(new)/W(old), is compared with a random number (a floating point number between 0 to 1).
www.science-park.info /simulation/mc14.html   (337 words)

  
 Advancing Physics - Boltzmann Factor
The gravitational potential energy of a molecule can increase randomly by that molecule borrowing energy from the other particles around it and the heat bath at temperature T. A complex process is perfectly described through the action of the exponential Boltzmann factor.
The particle is in equilibrium with a heat bath at temperature T. In the spirit of the dice game from chapter 14 in Advancing Physics A2 the particle has to borrow energy from the heat bath to jump up the energy levels.
This is increasingly difficult according to the Boltzmann factor rules.
advancingphysics.iop.org /teacher/revision/boltzmann.html   (514 words)

  
 chap1.html
You may notice that Boltzmann's constant is absent from this formula.
That is because of using natural thermodynamic units for entropy (dimensionless) and temperature (energy).
Boltzmann's constant is simply a conversion factor between the natural units of temperature (energy, e.g.
silas.psfc.mit.edu /introplasma/chap1.html   (1245 words)

  
 The Laws of Thermodynamics   (Site not responding. Last check: 2007-10-29)
As discussed in section 8.5 the base of the logarithm in equation 3 is chosen according to what units you wish to use for measuring entropy.
Deciding which laws to emphasize is to some extent a matter of taste, but one ought to consider such factors as simplicity and generality, favoring laws with a large number of predictions and a small number of exceptions.
In equilibrium, states are supposed to be occupied in accordance with the Boltzmann distribution law (equation 27).
www.av8n.com /physics/thermo-laws.htm   (13547 words)

  
 Boltzmann Distribution
Using Boltzmann factors, we can build another function which is of great use to thermal physics.
It is the sum over the Boltzmann factors associated with all of the allowed states.
Notice that the partition function acts as the normalization constant for the Boltzmann factor to be used as a measurement of probability
physics.tamuk.edu /~suson/html/3333/Boltzmann.html   (869 words)

Try your search on: Qwika (all wikis)

Factbites
  About us   |   Why use us?   |   Reviews   |   Press   |   Contact us  
Copyright © 2005-2007 www.factbites.com Usage implies agreement with terms.