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 | | Quantum mechanically, however, the electron is not a hard little point, but a fuzzy ball of probability; consequently, the classical calculation must break down when the distance x between the electron and the metal surface is so small that the wavefunctions of the conduction electrons begin to overlap with that of the outside electron. |
 | | Conduction electrons in a metal behave almost as free electrons, so the potential U(x) which the electrons see may be approximated as a simple square well of finite depth. |
 | | Electrons near the fermi level in the left metal are now at the same energy as unoccupied states in the right metal, and they can tunnel through the potential barrier between the metals, if the barrier thickness x is sufficiently small. |
| www.colorado.edu /physics/TZD/SolidStateChs/NewCh14solidsIIthurs.doc (14702 words) |
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