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| | More on Partition Function |
 | | There are actually several different types of partition function, each corresponding to different types of statistical ensemble (or, equivalently, different types of free energy.) The canonical partition function applies to a canonical ensemble, in which the system is allowed to exchange heat with the environment at fixed temperature, volume, and number of particles. |
 | | The partition function is a function of, firstly, the temperature T; and, secondly, the microstate energies E1, E2, E3, etc. The microstate energies are determined by other thermodynamic variables, such as the number of particles and the volume, as well as microscopic quantities like the mass of the constituent particles. |
 | | In a manner similar to the definition of the canonical partition function for the canonical ensemble, we can define a grand canonical partition function for a grand canonical ensemble, a system that can exchange both heat and particles with the environment, which has a constant temperature T, volume V, and chemical potential μ. |
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