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| | Chapter 2 |
 | | It is obvious that molecules in a gas are not prevented from rotating, nor is it realistic to expect a molecule that may be deformed by rotation not to vibrate, and indeed both occur simultaneously. |
 | | Although there is an increase in complexity when moving from diatomic to polyatomic molecules, the modifications to the theory for diatomic molecules are logical and not great; as such developments are covered in standard texts only brief mention shall be made of some aspects of polyatomic vibration. |
 | | If this is parallel to the axis of symmetry of the molecule as is the case in the stretch modes of carbon dioxide and the bend and symmetric stretch modes of water, then the selection rules are identical to those for diatomic molecules, namely that DJ = ±1, or DJ = ±1, ±2, ±3,... |
| web.ukonline.co.uk /akv/thesis/phd_ch2b.htm (1569 words) |
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