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| | Laser spectroscopy of nanometric gas cells |
 | | The Doppler effect plays an important role in the optical spectra of atomic or molecular species, from which one can analyse their characteristic emission frequencies. |
 | | In particular, if the atom absorbs simultaneously two photons of the same frequency, each travelling in counter-propagating directions, the Doppler shifts respectively associated with either absorption are exactly opposite, and their sum cancels, leading to a zero Doppler shift, whatever the atomic velocity may be [3]. |
 | | When the incident light is normal to the surface, the Doppler effect cancels for those atoms moving at grazing incidence: the light absorption becomes free of Doppler broadening, as has been demonstrated in thin cells of Cs gas at the D2 resonance line, |
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