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Topic: Ethanoyl chloride

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	reaction between acyl chlorides and ammonia - addition / elimination (Site not responding. Last check: 2007-10-12)
		Ethanoyl chloride is taken as a typical acyl chloride.
		Ethanoyl chloride reacts violently with a cold concentrated solution of ammonia.
		The first stage (the addition stage of the reaction) involves a nucleophilic attack on the fairly positive carbon atom by the lone pair on the nitrogen atom in the ammonia.
	www.chemguide.co.uk /mechanisms/addelim/ammonia.html (299 words)

	ACETAMIDE (ETHANAMIDE)
		dehydration of ammonium ethanoate; ammonia on ethanoyl chloride, ethanoic anhydride, or ethyl ethanoate.
		Acetamide is used as a solvent, plasticizer, and a wetting and penetrating agent and in lacquers, soldering flux and explosives.
		Amide is obtained by reaction of an acid chloride, acid anhydride, or ester with an amine.
	www.chemicalland21.com /industrialchem/organic/ACETAMIDE.htm (548 words)

	Types of Chemical Reaction, Definitions and Examples
		Methanol and butanoyl chloride ---> methyl butanoate and hydrogen chloride
		Methanol and ethanoyl chloride ---> methyl ethanoate and hydrogen chloride
		CH This example is the reverse of the earlier esterification reaction, and is usually carried out in the presence of potassium or sodium hydroxide, which then react with the acid formed to give the salt of the acid.
	www.sky-web.net /science/reaction-types.htm (1135 words)

	Acetyl Chloride
		Acetyl Chloride is an energetic acetylating agent, particularly in combination with aluminium chloride, for compounds that are difficult to acetylate.
		Acetyl chloride is a clear, corrosive and fuming liquid; melting point of -112 C, boiling point of 51-52 C, Refractive Index of 1.3890.
		Acetyl chloride is widely used as an acetylating agent in the synthesis of fine chemicals, agrochemicals and pharmaceuticals.
	www.greatvistachemicals.com /industrial_and_specialty_chemicals/acetyl_chloride.html (269 words)

	Explaining the reaction between acyl chlorides and ammonia - addition / elimination
		The ethanoyl chloride molecule is also planar (flat) around that carbon atom, and that leaves plenty of room for a nucleophile to attack either from above or below the plane of the molecule.
		As the lone pair on the nitrogen approaches the fairly positive carbon in the ethanoyl chloride, it moves to form a bond with it.
		The route involving the formation of hydrogen chloride is exactly in line with the water or alcohol mechanisms, but you do need to remember to react the HCl with excess ammonia.
	www.chemguide.co.uk /mechanisms/addelim/ammoniatt.html (797 words)

	ICSC 0210 - ACETYL CHLORIDE
		The vapour is heavier than air and may travel along the ground; distant ignition possible.
		The substance decomposes on heating and on burning producing toxic and corrosive fumes including hydrogen chloride (see ICSC 0163), phosgene (see ICSC 0007).
		Reacts violently with water, alcohols, acids, bases, certain powdered metals and many other compounds causing fire and explosion hazard.
	www.ilo.org /public/english/protection/safework/cis/products/icsc/dtasht/_icsc02/icsc0210.htm (501 words)

	CFCC Organic Chemistry (Site not responding. Last check: 2007-10-12)
		Ethanoyl Chloride + KSH review with explanations of key points
		Animated ethanoyl chloride reaction with sodium formate to make ethanoic methanoic anhydride
		Quiz on Acid Chlorides and Anhydrides Richard Banks
	www.freenet.tlh.fl.us /~pendarr/carboxylic_acids.html (207 words)

	ethanoyl chloride - Hutchinson encyclopedia article about ethanoyl chloride
		ethanoyl chloride is not available in the Hutchinson encyclopedia.
		You may also use the word browser links:
		This information should not be considered complete, up to date, and is not intended to be used in place of a visit, consultation, or advice of a legal, medical, or any other professional.
	encyclopedia.farlex.com /ethanoyl+chloride (86 words)

	alevelchemistry.co.uk :: View topic - chemistry (Site not responding. Last check: 2007-10-12)
		2 possible reagents to introduce the ethanoyl group into aspirin are ethanoyl chloride and ethanoic anyhdride
		Using curly arrows suggest mechanisms for the reaction of 2-hydroxybenzoic acid with each of these compounds
		Ethanoyl chloride is formed when ethanoic acid looses its OH group and it is replaced by a molecule of chlorine.
	www.alevelchemistry.co.uk /forum/viewtopic.php?p=101&sid=f2535d6da4ba981cbf6e1046437e31c2 (227 words)

	ACETYL CHLORIDE (ICSC)
		The vapour is heavier than air and may travel along the ground; distant ignition possible.
		The substance decomposes on heating and on burning producing toxic and corrosive fumes including hydrogen chloride (see ICSC 0163), phosgene (see ICSC 0007).
		Reacts violently with water, alcohols, acids, bases, certain powdered metals and many other compounds causing fire and explosion hazard.
	www.inchem.org /documents/icsc/icsc/eics0210.htm (454 words)

	Safety (MSDS) data for acetyl chloride
		Synonyms: acetic chloride, ethanoyl chloride, acetic acid chloride
		Appearance: colourless to light yellow liquid with a pungent and choking odour
		We have not verified this information, and cannot guarantee that it is up-to-date.
	physchem.ox.ac.uk /MSDS/AC/acetyl_chloride.html (197 words)

	University of Tennessee: Safety Information
		Corrosivity An aqueous solution that has a pH of less than or equal to 2, or greater than or equal to 12.5, is considered corrosive.
		Corrosive materials also include substances such as thionyl chloride, solid sodium hydroxide and some other non-aqueous acids or bases.
		Acetyl chloride Phosphorous (yellow) Benzoyl peroxide Potassium metal Bromine Sodium metal Calcium metal Thionyl chloride Lithium metal J.
	www.utmem.edu /safety/2wasteguide.html (5804 words)

	ethanoyl chloride - English dictionary meaning (Site not responding. Last check: 2007-10-12)
		1) n :colorless liquid acyl chloride (CH3COCl) that has a pungent odor
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	www.realdictionary.com /E/dir/ethanoylchloride.asp (56 words)

	Narrow Fabric Wholesalers,Types of Fabrics,Abaca Fabric,Fabrics Wholesalers,Abaca Fabrics India,Narrow Fabric ...
		The Term Used To Describe Fibres Of Cellulose Ethanoate (acetate) Wherein Between 74% And 92% Of The Hydroxyl Groups Of The Original Cellulose Are Ethanoylated (acetylated).
		Purified Cellulose Is Ethanoylated (acetylated) By Ethanoic Anhydride (acetic Anhydride) In The Presence Of A Catalyst (such As Sulphuric Acid Or Perchloric Acid) In A Solvent Such As Dichloromethane (methylene Chloride) Or Ethanoic (acetic) Acid.
		When The Hydrolysis Of Primary Cellulose Ethanoate (acetate) Is Allowed To Proceed Until Approximately 54% Of Combined Ethanoic (acetic) Acid Remains In The Product, The Cellulose Acetate Is Soluble In Propanone (acetone) And Is Sometimes Known As Acetone-soluble Cellulose Acetate.
	www.narrow-fabrics-manufacturers.com /glossary-of-products.html (1397 words)

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