| | Magnetic interactions and the co-operative Jahn-Teller effect in KCuF3 |
 | | Because of the small overlap in the orbitally-ordered plane, the difference in kinetic energy between the AF2 and ferromagnetic phases is relatively small, and the dominant contribution to the energy difference is the additional electron-nuclear attraction in the ferromagnetic phase. |
 | | In the ferromagnetic state, the contraction of majority (alpha) spin density on the F1 fluorine ion (centre left and centre right of the figure) is very large relative to that of the beta spin density. |
 | | For antiferromagnetic superexchange contacts, the lowering of kinetic energy is the dominant contribution, while in the equivalent ferromagnetic interaction in orbitally-ordered planes, the electron-nuclear repulsion predominates. |
| www.tcm.phy.cam.ac.uk /~mdt26/kcuf3/kcuf3.html (5319 words) |