| | INI : Abstracts : PDSW02 : The fluctuation & nonequilibrium free energy theorems, theory & experiment (Site not responding. Last check: 2007-10-22) |
 | | We discuss a number of simple consequences of the Fluctuation Theorems including the Second Law Inequality, the Kawasaki Identity and the fact that the dissipation function which is the subject of the FT, is a nonlinear generalization of the spontaneous entropy production, that is so central to linear irreversible thermodyanamics. |
 | | 2 The Fluctutation Theorem: In 1993 we discovered a relation, subsequently known as the Fluctuation Theorem (FT), which gives an analytical expression for the probability of observing Second Law violating dynamical fluctuations in small thermostatted nonequilibrium systems which are observed for a short period of time. |
 | | Quantitative predictions made by the Fluctuation Theorem regarding the probability of Second Law `violations' have been confirmed experimentally, both using molecular dynamics computer simulation and very recently in two laboratory experiments[1] which employed optical tweezers. |
| www.newton.cam.ac.uk /programmes/PDS/Abstract2/evans.html (312 words) |