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Topic: Formic acid


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In the News (Sun 22 Nov 09)

  
  Formic acid - LoveToKnow 1911
Its nitrile (prussic acid) has an acid character, a property not possessed by the nitriles of the other members of the series; and, by the abstraction of the elements of water from the acid,.
The free acid, when heated with concentrated sulphuric acid, is decomposed into water and pure carbon monoxide; when heated with nitric acid, it is oxidized first to oxalic acid and finally to carbon dioxide.
The esters of the acid may be obtained by distilling a mixture of the sodium or potassium salts and the corresponding alcohol with hydrochloric or sulphuric acids.
www.1911encyclopedia.org /Formic_acid   (706 words)

  
 Formic Acid
Formic acid is a colorless, fuming liquid with a highly pungent, penetrating odor.
Acute, overexposure to formic acid causes corrosion of the skin, eyes, and mucous membrane of the mouth, throat, and esophagus and may be associated with complications such as cardiovascular collapse and ischemic damage to the heart, liver and kidneys, swelling of the airway, and respiratory distress.
Before a worker is placed in a job with a potential for exposure to formic acid, a licensed health care professional should evaluate and document the worker's baseline health status with thorough medical, environmental, and occupational histories, a physical examination, and physiologic and laboratory tests appropriate for the anticipated occupational risks.
www.osha.gov /SLTC/healthguidelines/formicacid/recognition.html   (4091 words)

  
  Formic acid Summary
Formic acid occurs naturally in a variety of plants and fruits (the fruit of the soaptree), mammalian tissues, and insect venoms, including the bodies of red ants and the stingers of bees.
Formic acid is unique among the carboxylic acids in its ability to participate in addition reactions with alkenes.
Formic acid is of minor importance in the textile industry and in the tanning of leather.
www.bookrags.com /Formic_acid   (1794 words)

  
 The World Market for Formic Acid and Its Salts and Esters: A 2007 Global Trade Perspective
Combined, Chapters 3 and 4 present the complete picture for imports and exports of formic acid and its salts and esters to and from all major countries in the world.
Formic Acid and Its Salts and Esters as a category is defined in this report following the definition given by the United Nations Statistics Division Classification Registry using the Standard International Trade Classification, Revision 3 (SITC, Rev. 3).
The SITC code that defined formic acid and its salts and esters is 51374.
www.marketresearch.com /product/display.asp?productid=1364254&xs=r   (811 words)

  
 Silver Conservation
For this reason, treatment in a formic acid electrolyte is often used for silver that has the original surface preserved in the corrosion layer.
During electrolysis, the reduced silver corrosion layers regenerated on the surface of the metal in formic acid are left in granular or particulated layers, which are physically weak and tend to separate from the metallic core.
Because the corrosion layers are particulated, silver that is reduced in formic acid tends to be dark, brittle, and rigid.
nautarch.tamu.edu /class/anth605/File13.htm   (4021 words)

  
 003. Formic acid (FAO Nutrition Meetings Report Series 38a)
B. Neutralize 1 ml of formic acid with sodium hydroxide TS and add 2 drops of the acid in excess; then add about 1 ml of ferric chloride TS: a deep reddish orange colour results which turns to yellowish orange on the addition of mineral acids.
C. Place 2 ml of formic acid in a test-tube, add 5 ml of sulfuric acid and test the gas evolved with a lighted splinter: a blue flame characteristic of carbon monoxide is produced.
Formic acid (or formate) is apparently more toxic than other fatty acids, possibly owing to its enzyme-inhibiting activity.
www.inchem.org /documents/jecfa/jecmono/v38aje03.htm   (779 words)

  
 formic acid — FactMonster.com
Like other acids, it reacts with most alcohols to form esters and decomposes when heated; like other aldehydes, it is easily oxidized.
Formic acid occurs in the bodies of red ants and in the stingers of bees.
Formic acid is used industrially in textile dyeing, in leather tanning, and in coagulating latex rubber.
www.factmonster.com /ce6/sci/A0819183.html   (216 words)

  
 Documentation for Immediately Dangerous to Life or Health Concentrations (IDLHs) - 64186
Basis for original (SCP) IDLH: Because no data on acute inhalation toxicity are available on which to base an IDLH for formic acid, the chosen IDLH is based on an analogy with formaldehyde, which has an IDLH of 30 ppm.
However, the original IDLH for formic acid (30 ppm) is not being revised at this time.
The aliphatic acids and their esters toxicity and potential dangers.
www.cdc.gov /niosh/idlh/64186.html   (185 words)

  
 Mite-Away IIi
Working with formic acid as a mite control active ingredient is very different from nerve disruptors like synthetic pyrethroids (Apistan®) and organophosphates (Checkmite™).
Mite-Away II technology releases enough formic acid over three weeks to be an effective dose, charging the colony environment, but not enough to damage the colony health.
Likewise, when bees breathe in the formic acid vapor, the tracheal mites are exposed to formic acid and die.
miteaway.com /Mite-Away_IIi/mite-away_iii.html   (380 words)

  
 H2CO2 FORMIC ACID - Online Information article about H2CO2 FORMIC ACID
free acid, when heated with concentrated sulphuric acid, is decomposed into water and pure carbon monoxide; when heated with nitric acid, it is oxidized first to oxalic acid and finally to carbon dioxide.
The salts of the acid are known as for-mates, and are mostly soluble in water, those of silver and lead being the least soluble.
esters of the acid may be obtained by distilling a mixture of the sodium or potassium salts and the corresponding alcohol with hydrochloric or sulphuric acids.
encyclopedia.jrank.org /FLA_FRA/FORMIC_ACID_H2CO2.html   (877 words)

  
  formic - Search Results - MSN Encarta
Formic Acid, simplest of the organic acids, with the chemical formula HCOOH.
Carboxylic Acid, any of a class of organic compounds containing one, two, or several carboxyl (—COOH) groups.
- acid found in ants: a colorless corrosive liquid that occurs naturally in ants and some plants.
ca.encarta.msn.com /formic.html   (96 words)

  
 Midnite Bee-Beekeeper's: Tips
Formic acid gel is a slow release formulation of formic acid in a plastic pouch for control of tracheal mite and suppression of varroa mite in colonies of honeybees.
The formic acid gel pack must be removed from the hive at least four weeks (28 days) before the beginning of surplus honey flow to prevent contamination of marketable honey.
If all the formic acid has been evaporated from the packet so that only dry powder remains, the used gel pack can be disposed of in a sanitary landfill, or by incineration, or if allowed by State and local authorites, by burning.
www.mainebee.com /reports/formicacid.php   (951 words)

  
 Formic Acid   (Site not responding. Last check: )
Formic acid (CAS #64-18-6) is a colorless liquid that is used in the manufacturing of fumigants, animal feed additives, and commercial paint strippers.
Formic acid is used in textile dyeing and finishing, leather tanning, nickel plating baths, electroplating, coagulating rubber latex, regenerating old rubber, and dehairing and plumping hides.
Synonyms for formic acid are hydrogencarboxylic acid, and methanoic acid.
www.nsc.org /ehc/chemical/FormicAc.htm   (1029 words)

  
 EPA: Formic Acid (214900) Fact Sheet
Formic Acid is used to treat tracheal and varroa mites in honey bee hives.
The tolerance exemption for formic acid in honey and beeswax was established in February 1999 (40 CFR 180.1178).
Formic acid is approved for use as a pesticide solely within honeybee hives.
www.epa.gov /pesticides/biopesticides/ingredients/factsheets/factsheet_214900.htm   (945 words)

  
 AllRefer.com - formic acid (Organic Chemistry) - Encyclopedia
Formic acid occurs in the bodies of red ants and in the stingers of bees.
It can be made by the oxidation of formaldehyde; it is prepared commercially by heating carbon monoxide and sodium hydroxide to form sodium formate which, when carefully treated with sulfuric acid, yields formic acid.
Formic acid is used industrially in textile dyeing, in leather tanning, and in coagulating latex rubber.
reference.allrefer.com /encyclopedia/F/formicac.html   (245 words)

  
 EPA: Federal Register: Formic Acid; Proposed Tolerance Exemptions
Formic acid occurs naturally in honey at levels up to 138 parts per million (ppm), with natural concentrations found most often in the 9 to 100 ppm range, depending upon the source of the nectar.
Formic acid has an acute oral LD 50 of 1,100 mg/kg in rats; 700 mg/kg in mice; and 4,000 mg/kg in dogs, However, formic acid is a severe eye irritant, and corrosive to the skin.
The biochemical pesticide formic acid is exempted from the requirement of a tolerance in or on honey and beeswax when used to control tracheal mites in bee colonies, and applied in accordance with accepted apiarian practices.
www.epa.gov /fedrgstr/EPA-PEST/1997/February/Day-05/p2712.htm   (2857 words)

  
 Formic Acid - MOTM 2005
Formic acid is also present in a natural state in stinging nettles, and is is reponsible for the burning feeling on contact with them.
Formic acid is a colourless, fuming liquid that is miscible with water.
Formic acid is used in textile dyeing and finishing, leather tanning, nickel plating baths, electroplating, coagulating rubber latex, regenerating old rubber, and dehairing and plumping hides, and in some commercial paint strippers.
www.chm.bris.ac.uk /motm/formic/formich.htm   (621 words)

  
 NTP: Abstract for TOX-19 - Formic Acid
Formic acid occurs in a variety of plants and fruits, mammalian tissues, and insect venoms.
Formic acid also is an environmental contaminant of air and water and has been identified as the toxic intermediate (formate) in methanol poisoning.
Lesions related to exposure to formic acid consisted of squamous metaplasia and degeneration of the respiratory and olfactory epithelia, respectively.
ntp.niehs.nih.gov /index.cfm?objectid=072CE030-D41D-EC74-BAD89399317E5524   (546 words)

  
 .: Les Reines Chapleau :.
In Europe, formic acid is given, not only by slow diffusion methods, but often as rapid volatilisation.
For all treatments involving formic acid, a 65% acid concentration was used, even if the Swiss Beekeeping Research Center recommends 85% when applications are administered from the bottom of the hive.
Formic acid treatments were applied at intervals of 4 to 7 days, except for the last flash when it was decided to wait for good weather and more importantly for more of the last brood to be hatched.
www.reineschapleau.wd1.net /articles/flash.en.html   (2445 words)

  
 BASF - Specialty Intermediates
In the leather industry, formic acid is used in the dyeing process, for pickling, deliming and as an auxiliary in the tanning process.
Formic acid is used in the preservation of green feed/fodder.
In addition, formic acid is used in the disinfection of wood barrels for wine and beer due to its bactericidal properties.
www.basf.com /specialtyintermediates/formic_acid.html   (384 words)

  
 Tekion
Liquid fuels, such as formic acid or methanol, can be used directly on one side of a proton exchange membrane (PEM), and oxygen from the air is used on the other side.
Formic acid is abundant in nature and its name was derived from the scientific name for the red ant, Formica Rufa, which produces it in large quantities.
BASF is the world’s biggest producer of formic acid, although most of it is actually produced by others – by ants themselves.
www.tekion.com /business/index.htm   (470 words)

  
 NTP: Abstract for TOX-19 - Formic Acid
Formic acid occurs in a variety of plants and fruits, mammalian tissues, and insect venoms.
Formic acid also is an environmental contaminant of air and water and has been identified as the toxic intermediate (formate) in methanol poisoning.
Lesions related to exposure to formic acid consisted of squamous metaplasia and degeneration of the respiratory and olfactory epithelia, respectively.
ntp-server.niehs.nih.gov /index.cfm?objectid=072CE030-D41D-EC74-BAD89399317E5524   (546 words)

  
 Oilfield Glossary: Term 'formic acid'
An organic acid used in the stimulation of high-temperature oil and gas wells in which conventional hydrochloric acid systems cannot be adequately inhibited, or where contact time with tubulars is likely to be extended.
Formic acid has an advantage over HCl in that formic acid is easier to inhibit against pipe corrosion at temperatures as high as 400°F [204°C].
Formic acid is intermediate in strength between hydrochloric acid [HCl] and acetic acid.
www.glossary.oilfield.slb.com /Display.cfm?Term=formic%20acid   (110 words)

  
 Federal Register, Feb 5, 1997-re Formic Acid
Formic acid occurs naturally in honey at levels up to 138 parts per million (ppm), with natural concentrations found most often in the 9 to 100 ppm range, depending upon the source of the nectar.
The potential dietary exposure of the general public to formic acid residues resulting from its use in bee hives for the control of tracheal mites is not expected to raise background levels naturally found in honey and beeswax.
The biochemical pesticide formic acid is exempted from the requirement of a tolerance in or on honey and beeswax when used to control tracheal mites in bee colonies, and applied in accordance with accepted apiarian practices.
apis.ifas.ufl.edu /papers/FORMIC.HTM   (2906 words)

  
 www.kemira.com - Germany - Deutsch - Aktuell - Formics
The environmentally friendly formic acid is the simplest organic acid present in nature and in addition to ants, it can also be found in various other plant and animal species.
Formic acid is mostly used in chemical processing, pH-control, preservation of agricultural and industrial processes and cleaning applications.
Formic acid products can replace the non-prescribed antibiotics in animal feed and the objective of their use is to improve the feed quality and safety.
www.kemira.com /Germany/Deutsch/Aktuell/Formics   (331 words)

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