| | Air-Sea gas exchange (Scott Doney) (Site not responding. Last check: 2007-11-07) |
 | | Leon Phillips suggests that the air-sea exchange of trace gases such as CO can be modified by irreversible thermodynamic coupling phenomena and that the commonly used gas exchange relationships can incorrectly predict the magnitude and, under certain circumstances, the sign of air-sea trace gas fluxes. |
 | | I have worked out the physical basis for irreversible thermodynamic effects during air-sea exchange for both a generic liquid-gas interface and for the molecular boundary layers or sublayers adjacent to an air-water interface. |
 | | For insoluble trace gases such as CO the temperature contrast across the limiting region for air-sea exchange, the aqueous mass sublayer, is not great enough to have a measurable impact on the trace gas distributions, and irreversible effects do not need to be included in empirical air-sea gas exchange relationships. |
| www.cgd.ucar.edu /oce/doney/gas/gas.html (208 words) |