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| | Hydrocarbon "metabolism" |
 | | In this paper, we consider the "intermediary metabolism" of a hydrocarbon assembler, i.e., the set of reactions that permit processing of the feedstock molecules and their conversion into molecular tools (positionally controlled carbenes, radicals, and other reactive species). |
 | | The stiff hydrocarbons include a wide enough class of materials to be a very attractive goal (diamond, graphite, and structurally related materials are included in this class). |
 | | As the radical will have to approach the butadiyne quite closely during the radical addition, and as the hydrocarbon structure confining the butadiyne will also have to be in close proximity to the butadiyne, allowing close proximity between the silicon radical and the confining structure relaxes a significant design constraint. |
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