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| | Azeotropic mixture of perfluoroalkyl iodide and hydrogen fluoride, and method for isolating and purifying ... (Site not responding. Last check: 2007-11-05) |
 | | In these applications, for example, when 1,1,1,2,2-pentafluoroethyl iodide as the raw material is reacted with hydrogen fluoride, or when hydrogen fluoride is produced as a by-product in producing 1,1,1,2,2-pentafluoroethyl iodide, or when 1,1,1,2,2-pentafluoroethyl iodide is produced using hydrogen fluoride, there is formed a mixture containing 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride in a variable ratio. |
 | | After the solubility reached an equilibrium, the proportions of 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride in a phase of 1,1,1,2,2-pentafluoroethyl iodide and a phase of hydrogen fluoride, respectively were determined. |
 | | A layer of 1,1,1,2,2-pentafluoroethyl iodide (600 g) was withdrawn from a heterogeneous mixture of 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride, and was placed into a distillation apparatus made of SUS 316(rectification column with an inner diameter 20 mm and a length 120 cm, packing:SULZER laboratory packing, and number of plates:20). |
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