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Topic: Hydrogen selenide


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In the News (Wed 16 Dec 09)

  
 RIA - Hydrogen selenide
Hydrogen selenide may be produced as a by-product and liberated during processes where selenium compounds may be present for example, during the smelting of alloys, during lead battery manufacture and during the production of studio glass.
The OES for hydrogen selenide i.e 0.05 ppm 8-hour TWA has been withdrawn and in the meantime until a MEL is assigned to the gas, ACTS considers that the general requirement on employers under the Control of Substances Hazardous to Health (COSHH) Regulations 1999 will ensure adequate control of exposure to this substance.
Hydrogen selenide may also be produced as a by-product where selenium compounds are present such as during alloy smelting but it is expected to be negligible because of the relatively trace amounts of selenium likely to be present in the parent selenium.
www.hse.gov.uk /ria/chemical/h-selen.htm   (1619 words)

  
 Wikinfo | Hydride
In main group element hydrides electronegativity of an element respective to hydrogen determines the compound to be either of the first two types.
Hydrogen gas is liberated proportional to the applied temperature and pressure but not to the chemical composition.
Various metal hydrides are currently being studied for use as a means of hydrogen storage in fuel cell-powered electric cars and batteries.
www.wikinfo.org /wiki.php?title=Hydride   (969 words)

  
 Selenium Compounds | Technology Transfer Network Air Toxics Web site | US EPA
Acute (short-term) exposure to elemental selenium, hydrogen selenide, and selenium dioxide by inhalation results primarily in respiratory effects, such as irritation of the mucous membranes, pulmonary edema, severe bronchitis, and bronchial pneumonia.
Acute animal tests in rats, mice, and guinea pigs, have shown hydrogen selenide to have extreme toxicity from inhalation exposure, sodium selenite to have extreme toxicity from oral exposure, and elemental selenium to have low toxicity from oral exposure.
This LOAEL is from the critical study used as the basis for the CalEPA chronic reference exposure level for hydrogen selenide.
www.epa.gov /ttn/atw/hlthef/selenium.html   (1960 words)

  
 Unique Properties of Water
The reason for the high melting and boiling temperatures is the hydrogen bonding between water molecules that causes them to stick together and to resist being pulled apart which is what happens when ice melts and water boils to become a gas.
In the case of liquid water, because the hydrogen bonds suppress vibration, the temperature does not increase as much as it would without the presence of strong hydrogen bonds.
Because of the hydrogen bonding it is very difficult to separate the water molecules from the surface of a liquid to form a vapor.
core.ecu.edu /geology/woods/H2OUNEEK.htm   (1091 words)

  
 Hydrogen Selenide - H2Se - is used to prepare metallis selenides and organoselenium compounds. It is also used in ...
Hydrogen Selenide - H2Se - is used to prepare metallis selenides and organoselenium compounds.
It is also used in doping gas mixtures for the preparation of semiconductor materials containing a controlled amount of significant impurity.
Se - is used to prepare metallic selenides and organoselenium compounds.
www.c-f-c.com /gaslink/pure/hydrogen-selenide.htm   (84 words)

  
 Unit Outline
A hydrogen bond is a strong dipole-dipole force between molecules in which hydrogen atoms are bonded to highly electronegative atoms.
Hydrogen sulfide has a lower boiling point that hydrogen selenide and hydrogen selenide has a lower boiling point than
Substances where hydrogen is bonded to oxygen, nitrogen, or flourine have uncharacteristically high boiling points.
www.msu.edu /~odonne68/unit13.htm   (722 words)

  
 Hydrogen sulfide - Wikipedia, the free encyclopedia
Hydrogen sulfide burns to give the gas sulfur dioxide, which is more familiar to people as the odor of a burnt match.
As mentioned above, sulfur-reducing and sulfate-reducing bacteria derive energy from oxidizing hydrogen or organic molecules in the absence of oxygen by reducing sulfur or sulfate to hydrogen sulfide.
Hydrogen sulfide has been implicated in some of the 5 mass extinctions that have occured in geologic time in the Earth's past.
en.wikipedia.org /wiki/Hydrogen_sulphide   (2160 words)

  
 Documentation for Immediately Dangerous to Life or Health Concentrations (IDLHs) - 7783075
Human data: Although very toxic, no fatalities have been reported, possibly because hydrogen selenide is easily oxidized to red selenium on the surface of mucous membranes of the nose and throat [Friberg et al.
Concentrations of 1.5 ppm have been found to be intolerable due to eye and nasal irritation [Dudley and Miller 1941].
Basis for revised IDLH: The revised IDLH for hydrogen selenide is 1 ppm based on acute inhalation data in humans [Dudley and Miller 1941; Friberg et al.
www.cdc.gov /niosh/idlh/7783075.html   (192 words)

  
 Environmental Protection Agency
Acute exposure to hydrogen selenide may include garlic odor of the breath, metallic taste, dizziness, weakness, fatigue, nausea, and vomiting.
Acute exposure to hydrogen selenide may require decontamination and life support for the victims.
Note: Ingestion of hydrogen selenide gas is not expected to be a significant route of exposure.
yosemite.epa.gov /oswer/CeppoEHS.nsf/firstaid/7783-07-5?OpenDocument   (418 words)

  
 Hydride - Wikipedia, the free encyclopedia
According to IUPAC convention, by precedence (stylized electronegativity), hydrogen falls between group 15 and group 16 elements.
As the name suggests, the hydrogen is covalently bonded to more electropositive p-block (boron, aluminium and Group 4-7) elements and beryllium.
In these, molecules of hydrogen dissociate and hydrogen atoms settle in the octahedral or tetrahedral holes in the metal crystal lattice called the interstitial sites.
en.wikipedia.org /wiki/Hydride   (966 words)

  
 Common molecules #50157 - Reciprocal Net   (Site not responding. Last check: 2007-11-06)
Hydrogen Selenide is used in doping as mix for preparation of semiconductor materials.
Hydrogen Selenide is a colorless toxic gas with a foul penetrating odor that it is extremely flammable and can form explosive mixture with air.
It is used for the preparation of metallic selenides and organoselenium compounds.
www.reciprocalnet.org /recipnet/showsample.jsp?sampleId=27344203   (140 words)

  
 Risk Management Plan: Morrisville, PA Solkatronic Chemicals Plant
Hydrogen Selenide is manufactured under pressure by thermally reacting Hydrogen and Selenium to produce the finished product which is then packaged.
At least 500 pound of aggregate storage of Hydrogen Selenide on the rear loading dock of the facility.
HYDROGEN SELENIDE - WIth a line shear downstream in the process (INDOORS), a mitigated release of 0.117 pounds through a scrubber reaches an off-site receptor at 0.1 miles.
www.actionpa.org /fluoride/chemicals/rmp-morrisville.html   (866 words)

  
 Hydrogen selenide, H2Se, Physical properties, safety, MSDS, enthalpy, material compatibility, gas liquid equilibrium, ...   (Site not responding. Last check: 2007-11-06)
Hydrogen selenide, H2Se, Physical properties, safety, MSDS, enthalpy, material compatibility, gas liquid equilibrium, density, viscosity, flammability, transport properties
This application enables data on many gas molecules to be accessed rapidly.
No specific or significant industrial application for hydrogen selenide has been found.
encyclopedia.airliquide.com /encyclopedia.asp?GasID=56   (433 words)

  
 [No title]   (Site not responding. Last check: 2007-11-06)
The stationary source and regulated substances handled: The primary purpose of this facility is the manufacturing, purification, and fill of specialty gases used in the electronics and fiber optic industry.
The worst-case scenario(s) and the alternative release scenario(s), including administrative controls and mitigation measures to limit the distance for each reported scenario: Below is a description of the WCS: *With a loss of containment of a (TOXIC) and release of material over 10 minutes, the Toxic End Point would reach an off-site receptor.
*Hydrogen Selenide - By a loss of containment, a mitigated release through a scrubber reaches an off-site receptor.
www.rtknet.org /rmp/testdump2005/PA/fac100000024092   (598 words)

  
 Involvement of Superoxide Dismutases in the Response of Escherichia coli to Selenium Oxides -- Bébien et al. 184 ...
former gene is induced by superoxide, whereas hydrogen peroxide
Hydrogen peroxide activates the soxRS regulon in vivo.
DNA microarray-mediated transcriptional profiling of the Escherichia coli response to hydrogen peroxide.
jb.asm.org /cgi/content/full/184/6/1556   (4185 words)

  
 Chemical Names Beginning with the Letter H
Hydrogen peroxide, aqueous solution, with not less than 8% but less than 20% Hydrogen peroxide
Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 60% Hydrogen peroxide (stabilized as necessary)
Hydrogen peroxide and Peroxyacetic acid mixture, with acid(s), water and not more than 5% Peroxyacetic acid, stabilized
hazmat.dot.gov /pubs/erg/psn_h.htm   (260 words)

  
 Hydrogen Selenide   (Site not responding. Last check: 2007-11-06)
Hydrogen Selenide is used to prepare metallic selenides and organoselenium compounds.
It is also used in doping gas mixtures for the preparation of semiconductor materials containing a controlled amount of impurity.
For price, packaging, delivery and other information, click here and tell us your name, company name, address and telephones, the application for the gas, and the purity level and volume desired.
www.eastwestgases.com /gasspecs/hydrogenselenide.htm   (71 words)

  
 Chemistry : Periodic Table : hydrogen : compounds information
This section lists some binary compounds with halogens (known as halides), oxygen (known as oxides), hydrogen (known as hydrides), and some other compounds of hydrogen.
For each compound, a formal oxidation number for hydrogen is given, but the usefulness of this number is limited for p-block elements in particular.
In compounds of hydrogen (where known), the most common oxidation numbers of hydrogen are: 1, and -1.
www.webelements.com /webelements/elements/text/H/comp.html   (225 words)

  
 Chemistry : Periodic Table : hydrogen : compound data [hydrogen (I) selenide]
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular.
Hydrogen selenide (danger!!) can be made in the laboratory by the direct reaction of the elements but might best be made from aluminium selenide.
With considerable care, the reaction between aluminium selenide and water can be used in the laboratory to make hydrogen(II) selenide.
www.webelements.com /webelements/compounds/text/H/H2Se1-7783075.html   (402 words)

  
 ATMI - Products
The SDS2® Hydrogen Selenide gas source offers an improved alternate to vaporized selenium and provides several significant benefits.
Solid source vaporized materials, such as selenium, result in high maintenance in cleaning up all the deposited dopant in the ion source from the overall vaporization process.
Production use of the SDS2® Hydrogen Selenide gas source has been proven to produce a ten-fold increase in beam current capabilities.
www.atmi.com /Products/Products.asp?prodid=275   (105 words)

  
 Hydrogen Sulfide, Deuterium Sulfide and Hydrogen Selenide (Solubility Data Series, Vol 32)   (Site not responding. Last check: 2007-11-06)
Hydrogen Sulfide, Deuterium Sulfide and Hydrogen Selenide (Solubility Data Series, Vol 32)
Hydrogen Sulfide, Deuterium Sulfide and Hydrogen Selenide (Solubility Data Series, Vol 32) by P. Fogg
Hydrogen systems papers presented at the International Symposium on Hydrogen Systems 7 - 11 May 1985 Beijing China by
www.cook-books.org /books/42974hydrogen_sulfide_deuterium_sulfide_hydr...   (128 words)

  
 Selenide - Wikipedia, the free encyclopedia
The selenide ion is Se selenide is a chemical compound in which selenium serves as an anion with oxidation number of −2, much as sulfur does in a sulfide.
Similar to sulfide, for an aqueous solution, selenide ion, Se, is prevalent only in very basic conditions.
This page was last modified 16:39, 15 October 2006.
en.wikipedia.org /wiki/Selenide   (88 words)

  
 Amazon.com: Hydrogen Sulfide, Deuterium Sulfide and Hydrogen Selenide (Solubility Data Series): Books: Peter G. T. Fogg   (Site not responding. Last check: 2007-11-06)
Amazon.com: Hydrogen Sulfide, Deuterium Sulfide and Hydrogen Selenide (Solubility Data Series): Books: Peter G. Fogg
This item is not eligible for Amazon Prime, but over a million other items are.
Hydrogen Sulfide, Deuterium Sulfide and Hydrogen Selenide (Solubility Data Series) (Hardcover)
www.amazon.com /Hydrogen-Sulfide-Deuterium-Selenide-Solubility/dp/0080324819   (496 words)

  
 Wiley::Inorganic Reactions and Methods, Volume 1, The Formation of Bonds to Hydrogen (Part 1)   (Site not responding. Last check: 2007-11-06)
in the Preparation of Hydrogen Selenide by Cathodic Reduction.
in the Preparation of Hydrogen Telluride by Cathodic Reduction in Acid Electrolyte.
in the Reduction of Sulfur Dioxide to Hydrogen Sulfide.
www.wiley.com /WileyCDA/WileyTitle/productCd-0471186546,descCd-tableOfContents.html   (925 words)

  
 Haz-Map: Occupational Exposure to Hazardous Agents
Experimental animals show signs of respiratory irritation and die after 8 hour exposures of 1 mg/m3 (0.3 ppm).
Inhalation of hydrogen selenide by workers has caused eye, nose, and respiratory irritation.
[ACGIH] Hydrogen selenide "is probably the only selenium compound that might pose a health concern in the workplace." [ATSDR ToxFAQs] Possible frostbite from contact with liquid; [Pocket Guide] See "Selenium and compounds."
hazmap.nlm.nih.gov /cgi-bin/hazmap_generic?tbl=TblAgents&id=516   (173 words)

  
 Available Technologies - Office of Technology Management   (Site not responding. Last check: 2007-11-06)
The technology enables easy scaling to produce the large wafers that are required for photovoltaic solar cells.
It is also safer than other processes because it does not use toxic materials, such as hydrogen selenide, and provides uniform deposition over large working areas.
Usable at large scale/volume: This technology provides uniform deposition over large working areas and can be scaled up to produce a large volume and size of films.
www.otm.uiuc.edu /techs/techdetail.asp?id=143   (415 words)

  
 DOD Technologies, Inc
The PS-7 has set the global standard for fast response, reliable operation and maintenance free gas detection of the following gases:
DOD Technologies has introduced a new spot sample system called IsoSense.
Chlorine, Ethylene Oxide, Hydrogen, Hydrogen Chloride, Hydrogen Cyanide, Hydrogen Sulphide, Nitric Oxide, Nitrogen Dioxide, Oxygen, Ozone, and Sulphur Dioxide.
www.dodtec.com   (208 words)

  
 Physical properties of gases, safety, MSDS, enthalpy, material compatibility, gas liquid equilibrium, density, ...
For a given volume or mass of gas, calculate the equivalent in gaseous and liquid phase.
Calculate the density of the liquid phase at any point on the liquid-gas equilibrium curve for nitrogen, carbon dioxide, argon, hydrogen or oxygen.
Download the vapor pressure curve for some gases.
www.us.airliquide.com /en/business/products/gases/gasdata/index.asp   (163 words)

  
 The high-resolution absorption spectra of hydrogen selenide and hydrogen telluride in the vacuum ultraviolet: II. ...
The high-resolution absorption spectra of hydrogen selenide and hydrogen telluride in the vacuum ultraviolet: II.
Rydberg states of hydrogen selenide and deuterium selenide
In particular, reselling and systematic downloading of files is prohibited.
stacks.iop.org /0022-3700/19/3505   (248 words)

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