Hydrogensulfide is corrosive and penetrates the lattice of some steels and makes them brittle, leading to sulphide stress cracking - a concern especially for handling acid gas and sour crude in the oil industry.
Metalsulfides should not to be confused with sulfites, which are derived from the sulfiteion SO Hydrogensulfide burns to give the gassulfur dioxide, which is more familiar to people as the odor of a burnt match.
Hydrogensulfide is a colorless gas with a rotten-egg odor.
Hydrogensulfide exposure is assumed in these studies based on job title, work history or living near facilities emitting hydrogensulfide.
The main effects of short-term and long-term hydrogensulfide exposure in laboratory animals are nasal and lung irritation and damage and effects on the brain.
Hydrogensulfide is produced naturally by decaying organic matter and is released from sewage sludge, liquid manure, sulfurhot springs, and natural gas.
Hydrogensulfide is used to produce elemental sulfur, sulfuric acid, and heavy water for nuclear reactors.
Hydrogensulfide poisoning is not known to pose additional risk during the use of bronchial or cardiac sensitizing agents.
Hydrogensulfide is a flammable colourless gas with the characteristic odour of rotten eggs.
One gram of hydrogensulfide dissolves in 187 ml of water at 10°C, in 242 ml of water at 20°C, in 314 ml of water at 30°C, and in 405 ml of water at 40°C (calculated from Weast, 1977-78).
The analyser is calibrated using hydrogensulfide, sulfur dioxide, methyl mercaptan, and dimethyl sulfide permeation tubes, and a dual-flow gas dilution device capable of producing reference standard atmospheres as low as the limits of detection of the method.
Hydrogensulfide may be produced by a variety of commercial methods, including reacting dilute sulfuric acid with ironsulfite, heating hydrogen and sulfur into their vapour phase, and heating sulfur with paraffin.
Hydrogensulfide levels of 0.92 µg/g in blood, 1.06 µg/g in brain, 0.34 µg/g in kidney, and 0.38 µg/g in liver were detected at autopsy in a man who was overcome by hydrogensulfide after working for 5 min in a tank (Winek et al., 1968).
Water supplies with as little as 1.0 ppm (part per million) hydrogensulfide are corrosive, may tarnishcopper and silverware, and occasionally release a fl material that stains laundry and porcelain.
Hydrogensulfide is formed by sulfurbacteria that may occur naturally in water.
The hydrogensulfide is adsorbed onto the surface of the carbon particles.
ohioline.osu.edu /aex-fact/0319.html (909 words)
hydrogen sulfide. The Columbia Encyclopedia, Sixth Edition. 2001-05(Site not responding. Last check: 2007-10-07)
Hydrogensulfide is flammable; in an excess of air it burns to form sulfur dioxide and water, but if not enough oxygen is present, it forms elemental sulfur and water.
Hydrogensulfide is found naturally in volcanic gases and in some mineral waters.
Hydrogensulfide reacts with most metalions to form sulfides; the sulfides of some metals are insoluble in water and have characteristic colors that help to identify the metal during chemical analysis.
Hydrogen Sulfide(Site not responding. Last check: 2007-10-07)
Hydrogensulfide is released primarily as a gas and will spread in the air.
A small amount of hydrogensulfide is produced by bacteria in your mouth and gastrointestinal tract and by enzymes in your brain and muscle.
Because it is heavier than air, hydrogensulfide tends to sink, and because children are shorter than adults, they may be more likely to be exposed to larger amounts than adults in the same situations.
Hydrogensulfide is generated in the flow when sewage is allowed to stand for long period and become stagnant or septic.
Hydrogensulfide (H2S) gas is normally heavier than air, but when agitated, it can erupt from the confines of the pipe in levels of toxicity which paralyze the lungs.
As the flows converged, deadly hydrogensulfidegas was forced from the manhole into the atmosphere, enveloping Horatio in a "mushroom cloud" of lethal gas.
Hydrogensulfide is oxidized by photochemically-generated free radicals, especially hydroxy radicals.
The exposure to reduced-sulfur gases, predominantly hydrogensulfide, was considered the most plausible explanation of the neurotoxic effects in this study.
This is a report on a 20-month old infant exposed for a year to 0.6 ppmhydrogensulfide downwind from a burning tip gas ignition point for a colliery.
Hydrogensulfide is an extremely hazardousgas which can be immediately life threatening at high concentrations (300 mg/cu m or 200 ppm).
Hydrogensulfide is rapidly oxidized and may ignite in contact with a range of metaloxides, including barium peroxide,...
Hydrogensulfide may readily cause pipes and valves to corrode or become brittle, lines and fittings likely to contain hydrogensulfide should be inspected frequently and receive special attention, monitoring, and maintenance to prevent leaks.
Certain circumstantial data suggests that children may be more susceptible than adults to the acute effects of hydrogensulfide under high level exposures.
Relevancy to humans of the olfactory lesions seen in rodents to human is suggested by Hirsch and Zavala (1999) who report decreased persistent olfactory function in workers exposed chronically to hydrogensulfide.
Source Document -- Toxicological Review of HydrogenSulfide (U.S. This assessment was peer reviewed by scientists external to the U.S. Their comments have been evaluated carefully and incorporated in finalization of this IRIS summary.
If the developers behind H2PIA have their way, a hydrogen future may not be as far off as some predict.
George Monbiot April 28th, 2006 advocates large-scale hydrogen use in Britain for heating purposes in a recent article in the Guardian.
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www.technorati.com /tag/hydrogen (506 words)
Arizona Instrument - Jerome 631 Hydrogen Sulfide Analyzer(Site not responding. Last check: 2007-10-07)
The sensor's selectivity to hydrogensulfide eliminates interferences from sulfur dioxide, carbon dioxide, carbon monoxide, and water vapors.
Any hydrogensulfide in the sample is adsorbed by the sensor which registers a proportional change in electrical resistance.
The hydrogensulfide concentration is displayed on the LCD, where it remains until the next sample is taken.
Other human data: It has been reported that 170 to 300 ppm is the maximum concentration that can be endured for 1 hour without serious consequences [Henderson and Haggard 1943] and that olfactory fatigue occurs at 100 ppm [Poda 1966].
Basis for revised IDLH: The revised IDLH for hydrogensulfide is 100 ppm based on acute inhalation toxicity data in humans [Henderson and Haggard 1943; Poda 1966; Yant 1930] and animals [Back et al.
Hydrogensulfide in industry: occurrence, effects and treatment.
For an explanation of terms: Glossary of Gas Detecting Terms
HydrogenSulfide is a colorless, very flammable gas.
In low concentrations it smells like "rotten eggs" however the sense of smell is lost after 2-15 minutes of exposure making it impossible to smell dangerous concentrations.
www.amgas.com /h2s.htm (188 words)
Safety (MSDS) data for hydrogen sulfide(Site not responding. Last check: 2007-10-07)
Click here for data on hydrogensulfide in student-friendly format, from the HSci project