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Topic: Interhalogen


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In the News (Wed 30 Dec 09)

  
  Chemistry : Periodic Table : fluorine : chemical reaction data
The trifluoride chlorine(III) fluoride is also formed and the reaction does not go to completion.
, reacts with bromine, Br, in the gas phase to form the interhalogen species BrF.
F solvent to form the interhalogen species IF.
www.webelements.com /webelements/elements/text/F/chem.html   (237 words)

  
  Interhalogen Information
The interhalogens of form XY have physical properties intermediate between those of the two parent halogens.
Chlorine monofluoride (ClF), the lightest interhalogen compound, is a colorless gas with a normal boiling point of -100°C. Bromine monofluoride (BrF) has not been obtained pure - it dissociates into the trifluoride and free bromine.
This compound is the only interhalogen compound possible where the larger atom is carrying seven of the smaller atoms.
www.bookrags.com /wiki/Interhalogen   (573 words)

  
  Plasmaless dry contact cleaning method using interhalogen compounds - Patent 5888906
evacuating unreacted interhalogen compound and volatile by-product gases from the reaction chamber.
The interhalogen compound may be removed from or flushed-out of the reaction chamber through the vent 22 by introduction of an inert gas at the inlet 18, such as argon.
Interhalogens are useful in removing metal oxides that readily form a volatile halide in the presence of a interhalogen.
www.freepatentsonline.com /5888906.html   (3650 words)

  
 Plasmaless dry contact cleaning method using interhalogen compounds - Patent 7033946
Unreacted interhalogen compound and volatile by-product gases may then be removed from the reaction chamber.
evacuating unreacted interhalogen compound, the inert gas, and the volatile by-product gases from the reaction chamber, and
Interhalogen compounds generally exist in four stoichiometries: XY, XY and XY where X is the heavier halogen.
www.freepatentsonline.com /7033946.html   (3033 words)

  
 The Chemistry of the Halogens
The gas given off when one of these solutions is heated is collected and then redissolved in water to give relatively pure samples of the mineral acid.
Interhalogen compounds are formed by reactions between different halogens.
All possible interhalogen compounds of the type XY are known.
chemed.chem.purdue.edu /genchem/topicreview/bp/ch10/group7.php   (1786 words)

  
 Polymerization catalyst   (Site not responding. Last check: 2007-10-26)
The criticality of halogen and interhalogen and their availability at the last stage of catalyst preparation is not disclosed.
The new catalysts and catalyst component of this invention are obtained by contacting an organometallic compound, a transition metal compound and a halogen or interhalogen compound in the presence or absence of a oxide support.
Illustrative interhalogen compounds are ClF, ClF.sub.3, BrF, BrF.sub.3, BrF.sub.5, ICI, ICI.sub.3 and IBr.
www.emergenthomestore.com /techcat/lug_nut_retainer/polymerization_catalyst.html   (7058 words)

  
 Halogen-doped superconductive fullerenes   (Site not responding. Last check: 2007-10-26)
The method of the invention involves contacting the fullerene material with a quantity of interhalogen compound under conditions sufficient to result in doping of the fullerenes with at least one of the elements of the interhalogen compound.
In a preferred embodiment, the interhalogen compound is vaporized and the vapor of the interhalogen compound is contacted with the fullerene material, thereby doping the fullerene material.
In the method in which the interhalogen compound is vaporized prior to contact with the fullerene material, the interhalogen material is kept at room temperature or above so that the vapor pressure of the interhalogen is sufficient to result in halogen-doping of the fullerenes.
www.90minuta.com /inventions/halogen-doped_superconductive_fullerenes   (2836 words)

  
 Erodible sanitizing caulk
The composition of claim 1 wherein said sanitizer is selected from the group consisting of an aldehyde compound, an iodophor complex, a carboxylic acid, a quaternary ammonium salt, a peracid compound, an interhalogen, a phenolic compound, a surface active agent, a halogen releasing agent and mixtures thereof.
The composition of claim 1 wherein said hardener is selected from the group consisting of an amide compound, a nonionic surfactant, a starch compound, an inorganic salt, and mixtures thereof.
The composition of claim 10 wherein said sanitizer is selected from the group consisting of an aldehyde compound, an iodophore complex, a carboxylic acid, a quaternary ammonium salt, a peracid compound, an interhalogen, a phenolic compound, a surface active agent, a halogen releasing agent and mixtures thereof.
www.processpatrol.com /thermoplastic_welding_sleeve/erodible_sanitizing_caulk.html   (926 words)

  
 Interhalogen : MOOGLED
The interhalogens of form XY have physical properties intermediate between those of the two parent halogens.
This compound is the only interhalogen compound possible where the larger atom is carrying seven of the smaller atoms.
All attempts to form bromine heptafluoride have met with failure; instead, bromine pentafluoride and fluorine gas are produced.
www.moogled.net /default/page/1255964/Interhalogen.htm   (643 words)

  
 Interhalogen at AllExperts
They are all prone to hydrolysis, and ionise to give rise to polyatomic cations and anions.
*Chlorine monofluoride (ClF), the lightest interhalogen compound, is a colorless gas with a normal boiling point of -100°C. Bromine monofluoride (BrF) has not been obtained pure - it dissociates into the trifluoride and free bromine.
Similarly, iodine monofluoride is unknown - iodine reacts with fluorine to form a pentafluoride.
en.allexperts.com /e/i/in/interhalogen.htm   (655 words)

  
 geometric shapes of interhalogen compounds
Chemical Forums: Chemistry Forum, Chemistry Question, Chemistry Help > Chemistry Forums for Students of Chemistry > Inorganic Chemistry Forum (Moderator: hmx9123) > geometric shapes of interhalogen compounds
Topic: geometric shapes of interhalogen compounds (Read 571 times)
Is there a method to find the geometric shapes of interhalogen compounds such as ICl2 ICL4 ?
www.chemicalforums.com /index.php?topic=492.msg2138   (296 words)

  
 Generation of Interhalogen Fluorides under Mild Conditions: A Comparison of Sluggish and Reactive Interhalogen Fluorides   (Site not responding. Last check: 2007-10-26)
Generation of Interhalogen Fluorides under Mild Conditions: A Comparison of Sluggish and Reactive Interhalogen Fluorides
Interhalogen fluorides (XF; X = I, Br, or Cl) generated from xenon difluoride (XeF
A comparison of the above reactions with other methods reported in the literature to generate interhalogen fluorides is made.
pubs.acs.org /cgi-bin/abstract.cgi/joceah/1999/64/i04/abs/jo972319g.html   (241 words)

  
 Publications of Dr. R.P. Ravindranathan Kartha
Observations on the activation of methyl thioglycosides by iodine and its interhalogen compounds.
Kartha, K.P.R. and Field, R.A. Iodine and its interhalogen compounds: Versatile reagents in carbohydrate chemistry V. Synthesis of 1,2-trans-linked 1-thioglycosides from per-O-acetylated glycoses.
(Iodine and its interhalogen compounds: Versatile reagents in carbohydrate chemistry VI.) Tetrahedron Lett., 38 (47), 8233-8236, 1997.
www.niper.nic.in /Kartha.htm   (1080 words)

  
 Degeneration inhibited sanitizing complexes   (Site not responding. Last check: 2007-10-26)
Halophors or complexes of polyoxazolines or polyoxazines and halogens, interhalogens and pseudo-halogens, are described in U.S. Pat.
Component (b) of the compositions are polyhalide anions formed by the combination of interhalogens such as bromine chloride or iodine bromide with halide anions such as chloride or bromide.
The polyhalide is present in the complex when the interhalogen and halide are combined in a mole ratio of less than about 10:1, and preferably less than about 2.5:1.
www.sacnewsmonthly.com /invent/foldable_hand_cart/degeneration_inhibited_sanitizing_complexes.html   (3491 words)

  
 Spartanburg SC | GoUpstate.com | Spartanburg Herald-Journal   (Site not responding. Last check: 2007-10-26)
They react with each other to form interhalogen compounds.
Diatomic interhalogen compounds (BrF, ICl, ClF, etc.) bear strong superficial resemblance to the pure halogens.
The halogens show a number of trends when moving down the group - for instance, decreasing electronegativity and reactivity, increasing melting and boiling point.
www.goupstate.com /apps/pbcs.dll/section?category=NEWS&template=wiki&text=Halogen   (690 words)

  
 Cleaning/disinfecting process and composition
A composition characterized in that it comprises one or more interhalogens or sources thereof and one or more acids or sources thereof which are not appreciably oxidized by the interhalogen(s) is disclosed.
The interhalogen may be iodine chloride, iodine trichloride, iodine bromide, bromine chloride or a mixture thereof.
Although iodine chloride is the preferred interhalogen for the present purposes, the present invention is not so-limited.
www.devileye.net /catalog/hand-held_vibratory_massager/cleaning_disinfecting_process_composition.html   (2657 words)

  
 BSP :: Advances in Organic Synthesis Home Page
In organizing this multi-authored volume, I felt it would be most appropriate that the first four chapters deal with recent developments involving the well established, older, reagents (such as elemental fluorine, interhalogen monofluorides, hypervalent halogen mono-fluorides, and xenon difluoride).
The ensuing nine chapters delineate/describe/outline the progress in synthetic fluorination chemistry involving the more recently developed electrophilic and nucleophilic reagents (such as N-fluoropyridinium, onium polyhydrogen fluorides, Selecfluor, the chiral NF compounds, DAST and Deoxofluor), while the last three chapters focus on enzymatic synthesis and the organometallic/heteroatom chemistry aspects.
Interhalogen monofluorides (XF; X=Cl, Br or I) generated in situ from hypohalites or N-halosuccinimides and a source of fluoride ion are “sluggish” electrophiles.
www.bentham.org /aos/contabs/aos2.htm   (3675 words)

  
 Cornell College - Chemistry - Official Handouts
Thus, when chlorine, bromine, or iodine is bonded to oxygen, the halogen will have an oxidation number higher than 0.
Furthermore, in an interhalogen compound the halogen with the higher atomic number should be given the higher oxidation number.
First, when oxygen atoms in a compound are joined by an -O-O- bond the oxidation number of oxygen is -1.
www.cornellcollege.edu /chemistry/chemstds/oxidation.shtml   (199 words)

  
 HHMI Lab Safety: LCSS: CARBON MONOXIDE   (Site not responding. Last check: 2007-10-26)
Carbon monoxide is a reducing agent; it reacts violently with strong oxidizers.
It undergoes violent reactions with many interhalogen compounds such as ClF
CO reacts with many metals to form metal carbonyls, some of which may explode on heating, and reduces many metal oxides exothermically.
www.hhmi.org /about/labsafe/lcss/lcss20.html   (585 words)

  
 Chemistry: The Central Science, Chapter 22, Section 4
These compounds are the simplest examples of interhalogens, compounds formed between two different halogen elements such as ClF and IF With one exception, the higher interhalogen compounds have a central Cl, Br, or I atom surrounded by 3, 5, or 7 fluorine atoms.
The geometries of interhalogen compounds can be predicted with good success by using the VSEPR model.
Because the interhalogen compounds contain a halogen atom in a positive oxidation state, they are exceedingly reactive.
wps.prenhall.com /wps/media/objects/3313/3392904/blb2204.html   (1947 words)

  
 Ravi Kartha
He returned to India in 2003 to take up the post of a Professor of Medicinal Chemistry with the current addres: Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Phase X, Sector 67, Mohali-160 062, Punjab, India.
Use of Iodine and its Interhalogen Compounds in Carbohydrate Chemistry
Iodine has been proved particularly suitable for acetylation of mono- and disaccharides such as galactose, glucose mannose, lactose, etc. On a 50-gram scale 5-10 mg of iodine per gram of sugar would be sufficient for acetylation.
www.uea.ac.uk /cap/carbohydrate/CCCPeople/Ravi/welcome.htm   (468 words)

  
 [No title]   (Site not responding. Last check: 2007-10-26)
The product is dificult to obtain pure since IF disproportionates at toom temperature to form iodine, I2, and IF5.
Fluorine, F2, reacts with bromine, Br2, in the gas phase to form the interhalogen species BrF.
The product is difficult to obtain pure since BrF disproportionates at toom temperature to form bromine, Br2, and BrF3 and BrF5.
www.lycos.com /info/fluorine--f2.html   (179 words)

  
 IngentaConnect Inductively Coupled Plasma Etching in ICl- and IBr-Based Chemistr...   (Site not responding. Last check: 2007-10-26)
High-density plasma etching of GaAs, GaSb, and AlGaAs was performed in ICl/Ar and IBr/Ar chemistries using an Inductively Coupled Plasma (ICP) source.
GaSb and AlGaAs showed maxima in their etch rates for both plama chemistries as a function of interhalogen percentage, while GaAs showed increased etch rates with plasma composition in both chemistries.
Etch rates of all materials increased substantially with increasing rf chuck power, but rapidly decreased with chamber pressure.
www.ingentaconnect.com /content/klu/pcpp/2000/00000020/00000003/00228096;jsessionid=7rt3hb24u6m4.alice   (277 words)

  
 Perodic Table Information   (Site not responding. Last check: 2007-10-26)
The trifluoride chlorine(III) fluoride is also formed and the reaction does not go to completion.
Under more forcing conditions, excess fluorine reacts with chlorine, Cl, at 350°C and 225 atmospheres pressure to form the interhalogen species ClF
Chlorine, Cl, reacts with bromine, Br, in the gas phase to form the unstable interhalogen species bromine(I) chloride, ClBr.
www.theperiodicelements.com /elements/view/Cl/rof.html   (150 words)

  
 Charge Transfer Complexes   (Site not responding. Last check: 2007-10-26)
The structure and bonding of charge transfer complexes between unsaturated olefins or non-bonding electron pairs and halogen X
or interhalogen XY molecules have caused considerable interest in the last decade.
These complexes have proven to be elusive and challenging for both experimentalists and theoreticians.
www.sc.ehu.es /powgep99/dcytp/teoricos/research/chargetrans.htm   (256 words)

  
 [No title]   (Site not responding. Last check: 2007-10-26)
Which, if any, of the following generalized formulas does not exist for interhalogen compounds?
All the above can represent stable interhalogen compounds.
When you have completed all the questions and reviewed your answers, press the button below to grade the test.
chemserv.venturacollege.edu /doliver3/chem1b/quiz/pquiz14.html   (383 words)

  
 Fluorine   (Site not responding. Last check: 2007-10-26)
Fluorine reacts with Chlorine (Cl) at 225°C to form the interhalogen species ClF.
Fluorine also reacts with Bromine (Br) in the gas phase to form the interhalogen species BrF.
F solvent to produce the interhalogen species IF.
www.chem.shef.ac.uk /chm131-2003/chb03ar/Fluorine.html   (396 words)

  
 HHMI Lab Safety: LCSS: HYDROGEN   (Site not responding. Last check: 2007-10-26)
Warming of liquid hydrogen contained in an enclosed vessel to above its critical temperature can cause bursting of that container.
Hydrogen is a reducing agent and reacts explosively with strong oxidizers such as halogens (fluorine, chlorine, bromine, iodine) and interhalogen compounds.
Because of its flammable and gaseous nature, hydrogen should be handled using the "basic prudent practices" of Chapter 5.C, supplemented by the additional precautions for work with flammable compounds (Chapter 5.F) and for work at high pressure (Chapter 5.H).
www.hhmi.org /about/labsafe/lcss/lcss49.html   (450 words)

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