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| | 94-207 |
 | | In particular, by contrast with the traditional statistical mechanics of finite systems, it accommodates the {\it phase structure} of matter, as manifested not only by the singularities in thermodynamic potentials, but also by the coexistence of equilibrium states with different microstructures. |
 | | Hence, the standard concept of entropy as a structural property of an operationally determinable microstate [5, Ch.5] is inapplicable to it; and therefore the proposed extension [6,7] of this concept to non-observable objects has a subjective component. |
 | | \vskip 0.2cm (1) In the case of a normal physical system, a microstate corresponds to a density matrix, ${\rho},$ whose explicit form may be operationally determined, and the entropy is a function, $-kTr({\rho}{\log}{\rho}),$ of this state, which provides a measure of its disorder [2, P.57]. |
| www.ma.utexas.edu /mp_arc/papers/94-207 (3117 words) |
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