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Topic: Oxyanion


In the News (Sat 28 Nov 09)

  
  sparks00jpn
Sparks, D. New frontiers in elucidating the kinetics and mechanisms of metal and oxyanion sorption at the soil mineral/water interface.
New frontiers in elucidating the kinetics and mechanisms of metal and oxyanion sorption at the soil mineral/water interface
An understanding of the kinetics and mechanisms of metal and oxyanion sorption on soil minerals and soils is fundamental in assessing the speciation, mobility, and bioavailability of metals and oxyanions in natural systems.
ag.udel.edu /SoilChem/sparks00jpn.html   (275 words)

  
 Oxyanion-catalyzed polymerization - Patent 4588795
By conjugate acid is meant the acid formed by protonating the catalytic oxyanion; for example, the conjugate acid of acetate anion is acetic acid, and that of biacetate anion is acetic acid dimer.
Oxyanion salts which are operable in the present invention contain cations that are inert under polymerizing conditions, yet render the catalyst available in the polymerizing medium; the medium can include one or more solubilizing agents, such as crown ethers.
Oxyanion sources which are particularly useful in the present invention include salts of carboxylic and bicarboxylic acids, sulfinic acids, phosphinic and phosphoric acids, phenols and biphenols, nitrous and cyanic acids, trihydrocarbylsilanols, and higher oligomeric forms of these acids, having the aforesaid pKa.
www.freepatentsonline.com /4588795.html   (5401 words)

  
 Structural determinants for ligand binding and catalysis of triosephosphate isomerase -- Kursula et al. 268 (19): 5189 ...   (Site not responding. Last check: 2007-09-16)
and it is observed to bind with its aldehyde oxygen in an oxyanion
Polarizing the carbonyl oxygen weakens the C-H bond of the carbon adjacent to the carbonyl group [40,41].
Oxyanion hole 1 is formed by NZ of Lys13 and NE2 of His95.
content.febsjournal.org /cgi/content/full/268/19/5189   (4477 words)

  
 Oxyanion Binding Alters Conformation and Quaternary Structure of the C-terminal Domain of the Transcriptional Regulator ...
Oxyanion Binding Alters Conformation and Quaternary Structure of the C-terminal Domain of the Transcriptional Regulator ModE.
The residues of ModE directly involved in oxyanion binding are marked with triangles, shaded to indicate the use of a side chain functional group and open where a main chain amide is used for binding.
Only those sites at the dimer interface that bind 6 oxyanions are shown; the other sites are buried at the trimer interface behind subunit A in one case and subunit D in the other.
www.jbc.org /cgi/content/full/276/23/20641   (4893 words)

  
 X-ray snapshots of serine protease catalysis reveal a tetrahedral intermediate - Nature Structural & Molecular ...
An oxyanion hole, consisting of the peptide amide of the active site serine and a neighbouring glycine, was identified, and hydrogen bonding in the oxyanion hole was suggested to stabilize the two proposed tetrahedral intermediates on the catalytic pathway.
The refined distances between the 'oxyanion' of the tetrahedral intermediate and the amide nitrogens of Gly 193 and Ser 195 were 2.9 Å and 2.6 Å, respectively (Fig.
Furthermore, the oxyanion is positioned 3.0 Å from the carbonyl oxygen of Cys 191 (Fig.
www.nature.com /nsmb/journal/v8/n8/full/nsb0801_689.html   (3866 words)

  
 CHAPTER7 / REVIEW#2 / COVALENT COMPOUDS Name_______________
To name such an acid, first write a form of the root of the name of the oxyanion.
If the oxyanion name ends in -ate, name the acid by adding the suffix -ic to the root.
If the oxyanion name ends in -ite, name the acid by adding the suffix -ous to the root.
www.awhs.org /zhaurova/rev2cov.htm   (770 words)

  
 Effects of the Metalloid Oxyanion Tellurite (TeO32-) on Growth Characteristics of the Phototrophic Bacterium ...
Effects of the Metalloid Oxyanion Tellurite (TeO32-) on Growth Characteristics of the Phototrophic Bacterium Rhodobacter capsulatus -- Borghese et al.
oxyanion from the medium and accumulate it in the cytoplasm.
Identification of intrinsic high-level resistance to rare-earth oxides and oxyanions in members of the class Proteobacteria: characterization of tellurite, selenite, and rhodium sesquioxide reduction in Rhodobacter sphaeroides.
aem.asm.org /cgi/content/full/70/11/6595   (4030 words)

  
 Nomenclature
If the oxyanion has one less O than the “-ate” ion, _______ite.
If the oxyanion has one hydrogen, the charge increases by +1, and the name of the ion is hydrogen________.
If the oxyanion has two hydrogens, the charge increases by +2, and the name of the ion is dihydrogen________.
faculty.mdc.edu /lrodicio/images/nomenclature.htm   (207 words)

  
 Microfluidization of calcium/oxyanion-containing particles - US Patent 5342609   (Site not responding. Last check: 2007-09-16)
wherein M is a paramagnetic metal ion or stoichiometric mixture of paramagnetic metal ions, X is a simple anion, Y is an oxyanion, tetrahedral oxyanion, carbonate, or mixtures thereof, n is from 1 to 10, m is from 1 to 10, s is≥1, and r is adjusted as needed to provide charge neutrality; and
The tetrahedral oxyanions used in the present invention may optionally include radiopaque metals or radioactive metals.
Suitable tetrahedral oxyanions are nonoxidizing and stable to hydrolysis.
www.patentstorm.us /patents/5342609.html   (7108 words)

  
 Naming Inorganic Compounds
There are a large number of oxyanions, which makes it difficult to remember all of their names.
The rules for naming oxyanions and the names for the most important oxyanions are given below.
The ending -ite is used for the oxyanion with the same charge, but one less oxygen than the -ate oxyanion.
www.chemistry.ohio-state.edu /~woodward/ch121/ch2_naming.htm   (543 words)

  
 Tracking interactions that stabilize the dimer structure of starch phosphorylase from Corynebacterium callunae: Roles ...   (Site not responding. Last check: 2007-09-16)
However, extrapolation to infinite [oxyanion] must be made with caution (hence, the broken lines) because of the additional lyotropic anion effect.
oxyanion, the R242A and R234A mutants were 3.8- and 6.2-fold
enzyme when oxyanion is present) being as large as 2.2 m.
content.febsjournal.org /cgi/content/full/270/10/2126   (6144 words)

  
 A conserved catalytic residue in the ubiquitin-conjugating enzyme family -- Wu et al. 22 (19): 5241 -- The EMBO Journal   (Site not responding. Last check: 2007-09-16)
Model for oxyanion stabilization by conserved E2 asparagine residue.
Ubc1 in the model of the Ubc1–Ub thiol ester (Hamilton et al., 2001) was replaced by Ubc13 and the N79 side chain was modeled in a conformation suitable for oxyanion stabilization.
Bryan,P., Pantolizno,M.W., Quill,S.G., Hsiao,H.-Y. and Poulos,T. (1986) Site-directed mutagenesis and the role of the oxyanion hole in subtilisin.
embojournal.npgjournals.com /cgi/content/full/22/19/5241   (5755 words)

  
 Functional Characteristics of the Oxyanion Hole in Human Acetylcholinesterase -- Ordentlich et al. 273 (31): 19509 -- ...
Functional Characteristics of the Oxyanion Hole in Human Acetylcholinesterase -- Ordentlich et al.
The contribution of the oxyanion hole to the functional architecture and to the hydrolytic efficiency of human acetylcholinesterase
Energetic and Structural Consequences of Perturbing Gly-193 in the Oxyanion Hole of Serine Proteases
www.jbc.org /cgi/content/abstract/273/31/19509   (583 words)

  
 Energy Citations Database (ECD) - Energy and Energy-Related Bibliographic Citations
Availability information may be found in the Availability, Publisher, Research Organization, Resource Relation and/or Author (affiliation information) fields and/or via the "Full-text Availability" link.
A rare earth oxide matrix (composition of matter) is formed which emits (upon heating) heavy metal oxide anions (oxyanions) into a gas phase, wherein the anions are emitted with high intensity, and wherein longevity of life of the composition of matter is retained.
The matter is formed by blending a major component of a rare earth oxide, europium oxide (Eu{sub 2}O{sub 3}) or ytterbium oxide (Yb{sub 2}O{sub 3}), with a minor component of a barium (Ba), calcium (Ca) or strontium (Sr) salt of a heavy metal oxyanion.
www.osti.gov /energycitations/product.biblio.jsp?osti_id=215236   (214 words)

  
 Substrate- and pH-dependent contribution of oxyanion binding site to the catalysis of prolyl oligopeptidase, a paradigm ...
Substrate- and pH-dependent contribution of oxyanion binding site to the catalysis of prolyl oligopeptidase, a paradigm of the serine oligopeptidase family -- Szeltner et al.
Substrate- and pH-dependent contribution of oxyanion binding site to the catalysis of prolyl oligopeptidase, a paradigm of the serine oligopeptidase family
Institute of Enzymology, Biological Research Center, Hungarian Academy of Sciences, Budapest.
www.proteinscience.org /cgi/content/abstract/9/2/353   (541 words)

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