| | COMP 237 - Computation of titration curves for sodium polyacrylate using a boundary integral/statistical mechanical ... (Site not responding. Last check: 2007-10-09) |
 | | Hydrogels such as Sodium Polyacrylate possess a number of important physical and chemical properties that ultimately derive from the dissociation of protons from COOH groups distributed throughout the cross-linked polymer, and the subsequent formation of an ion atmosphere. |
 | | Given the work of charging polyacrylic acid, a statistical mechanical computation of the titration curve is performed. |
 | | In order to compute the work of charging partially ionized polyacrylic acid, the linearized Poisson-Boltzman equation is solved using a Boundary Integral strategy while treating the polymeric chains as a sequence of non-overlapping spheres, with non-uniform spacing, and lying along a linear segment. |
| membership.acs.org /C/COMP/pastprograms/spr03/P579519.HTM (240 words) |