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Topic: Tertiary Amine


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In the News (Sun 29 Nov 09)

  
  Amines - LoveToKnow 1911
By the action of ammonia on the alkyl iodides a complex mixture of primary, secondary and tertiary amines, along with a quaternary ammonium salt, is obtained, the separation of which is difficult.
The mixed secondary amines are prepared by the action of alkyl iodides on the primary amines, or by heating salts of the primary amine with alcohols under pressure.
The aromatic amine resembling the aliphatic amines is benzylamine, C 6 H 5 �CH 2 �NH 2, which may be prepared by reducing benzonitrile in alcoholic solution by means of zinc and acetic acid (0.
www.1911encyclopedia.org /Amines   (2199 words)

  
 Amine - Wikipedia, the free encyclopedia
Tertiary amines of the type NHRR' and NRR'R" are chiral: the nitrogen atom bears four distinct substituents counting the lone pair.
Tertiary amines cannot be acylated due to the absence of a replaceable hydrogen atom.
By reduction of quaternary ammonium cations to tertiary amines in the Emde degradation.
en.wikipedia.org /wiki/Amine   (1664 words)

  
 Amine - Biocrawler   (Site not responding. Last check: 2007-11-04)
Amines have structures resembling ammonia, where one or more hydrogen atoms are replaced by alkyl groups or other groups where the nitrogen is bonded to a carbon atom in the group (groups symbolized by R below).
A tertiary amine molecule whose substituents are distinct is a chiral object: the nitrogen has four distinct substituents (counting the lone pair) with no plane of symmetry.
Aromatic amines are amines in which the nitrogen is connected to an aromatic ring as in anilines.
www.biocrawler.com /encyclopedia/Amine   (758 words)

  
 U.S. Patent: 5124300 - Carbonylation catalyst system - June 23, 1992
Tertiary amines are basic compounds and so might be expected to have a marked inhibitory effect upon the performance of the acid-containing catalyst system.
When the tertiary amine is present in catalytic quantities, the number of equivalent of tertiary amine per mole of protons is preferably in the range of from 0.1 to 200, more preferably, 0.5 to 100, especially 1 to 50.
When the tertiary amine is present in solvent quantities, the number of equivalents of tertiary amine per mole of protons is preferably in the range of from 1 to 2,500, more preferably 1.5 to 1500, especially 10 to 1000.
www.everypatent.com /comp/pat5124300.html   (5865 words)

  
 amine Information Center - amine
Amines are organic compounds containing nitrogen as the heterocyclic amines key atom in the amine functional di methyl ethanol amine group.
A amine value tertiary amine molecule whose substituents are distinct is a chiral object: the nitrogen has four distinct substituents (counting the lone pair) with no plane amine chemistry of symmetry.
Aromatic amines are amines in amine mp3 which the nitrogen is connected to an aromatic ring as in anilines.
www.scipeeps.com /Sci-Chemistry_Topics_A_-_An/amine.html   (773 words)

  
 Amine Information Center - amine
Amines are organic amine 400, 2,4-d weed killer compounds containing nitrogen as the key atom in the amine functional group.
The pairs of dots on the N atoms in the chemical reactions shown amine regenerator materials in this article represent ketene amine reaction the lone electron coco amine pairs on the nitrogens amine drugs in di methyl ethanol amine the amines.
A tertiary amine molecule whose substituents are distinct is a chiral object: amine unit the nitrogen has four distinct substituents (counting the lone pair) basic amine order of with no plane of symmetry.
www.scipeeps.com /Sci-Biochemistry_Topics_A/Amine.html   (766 words)

  
 an introduction to amines
The easiest way to think of amines is as near relatives of ammonia, NH In amines, the hydrogen atoms in the ammonia have been replaced one at a time by hydrocarbon groups.
In a tertiary amine, all of the hydrogens in an ammonia molecule have been replaced by hydrocarbon groups.
Although the tertiary amines don't have a hydrogen atom attached to the nitrogen and so can't form hydrogen bonds with themselves, they can form hydrogen bonds with water molecules just using the lone pair on the nitrogen.
www.chemguide.co.uk /organicprops/amines/background.html   (1063 words)

  
 Electrophotographic photoconductors and tertiary amine compounds having condensed polycyclic group for use in the same ...
The tertiary amine compound as claimed in claim 1, wherein said condensed polycyclic hydrocarbon group is selected from the group consisting of a naphthyl group, a fluorenyl group, an acenaphthenyl group, an anthryl group, a pyrenyl group, a phenanthryl group, a chrysenyl group and a fluoranthenyl group.
The tertiary amine compound as claimed in claim 1, wherein the alkyl group in said substituted group in said substituted group represented by R.sup.1 or R.sup.2 is an alkyl group having 1 to 6 carbon atoms.
The tertiary amine compound as claimed in claim 1, wherein said substituent of said phenyl group represented by R.sup.1 and R.sup.2 is an alkyl group having 1 to 6 carbon atoms, an alkoxyl group having 1 to 6 carbon atoms, or a halogen.
www.freepatentsonline.com /5550293.html   (6143 words)

  
 amino group - HighBeam Encyclopedia
Amines are derivatives of the inorganic compound ammonia, NH When one, two, or all three of the hydrogens in ammonia are replaced by an alkyl or aryl group, the resulting compound is known as a primary, secondary, or tertiary amine, respectively.
Amines can be synthesized by reacting ammonia with an alkyl halide and neutralizing the resulting alkyl ammonium salt with an alkali, e.g., sodium hydroxide.
Amines can also be prepared by the reaction of ammonia with an alcohol or by the reduction of any of a variety of compounds containing nitrogen in a higher oxidation state.
www.encyclopedia.com /doc/1E1-aminogro.html   (461 words)

  
 [No title]
Amines are formed from ammonia when one or more of the hydrogen atoms are substituted by alkyl or aryl groups.
Amines are named by naming the attached groups as alkyl or aryl groups and add the word, amine.
Tertiary amines do not enter this reaction because they do not have a hydrogen atom that can be lost to form water.
www.siue.edu /~jshen/CH120/CH120CH15.doc   (1451 words)

  
 MVS Solutions - Method for Preparing Chiral Amines
A method for preparing chiral amine, comprising: reacting ketoxime represented by formula 1, a palladium catalyst, a lipase, an acyl donor, and a tertiary amine in an organic solvent to prepare an amide of formula IV ; and hydrolyzing the amide.
In this method, a chiral amine was prepared as optically pure amide by dynamic kinetic resolution from the mixture of racemic 1-phenylethylamine as a substrate, palladium as a racemization catalyst, and lipase as a selective acylation catalyst.
The final chemical structure of chiral amine derivative was identified by 1H NMR and 13C-NMR, and the optical purity which were determined with a chiral high-performance liquid chromatography (equipped with Whelk-01 or Chiraldex OD-H column), was 95% ee, and the yield was 80%.
www.mvssolutions.com /PBC_03-048151.html   (1719 words)

  
 Simdean Envirotec Foundry Amine Removal
Amines, or ammonia bases, are derivatives of ammonia in which one or more of the hydrogen atoms has been replaced by a hydrocarbon radical.
The chemical properties of these three classes of amine compound differ considerably, and their properties also differ to some extent according to whether the substituting radicals are (1) all aliphatic, (2) all aromatic or (3) a combination of aliphatic and aromatic.
The amines of the aliphatic series are volatile flammable substances, the lower members of the series being gases or liquids with low boiling points, soluble in water and alkaline to litmus.
www.simdean-environmental.co.uk /foundry.htm   (1276 words)

  
 Amines
The Amine family is a family of Organic compounds that have at least one sp3 hybridized Nitrogen bonded to as few as one hydrocarbon group and as many as four hydrocarbon groups.
In addition, the Nitrogen atom of the primary,secondary, and tertiary amines has a lone pair of electrons that is often in the presence of a more acidic substance capable of donating the lone pair in forming a fourth bonding pair.
Tertiary Amines are the least soluble since they have no Hydrogen bonded to the Nitrogen that could Hydrogen bond with water molecules.
members.aol.com /logan20/amines.html   (728 words)

  
 Aqueous coating composition from aminoplast and reaction product of tertiary amine and polymer containing terminal ...
The composition of claim 3 wherein said tertiary amine is selected from the group consisting of: trimethyl amine, dimethyl ethanol amine, methyl diethanol amine, ethyl methyl ethanol amine, dimethyl propyl amine, dimethyl 3-hydroxy-1-propyl amine, dimethyl 2-hydroxy-1-propyl amine, dimethyl 1-hydroxy-2-propyl amine, and mixtures thereof.
The amount of tertiary amine used is determined by the epoxy equivalent of the particular epoxy resin employed and is at least 0.75 equivalent, and preferably between 0.9 and 1.1 equivalents, per epoxy group.
At lower levels of amine use the residual epoxy groups of the epoxy resin are subject to further reaction in the highly basic reaction medium.
www.freepatentsonline.com /4076676.html   (5836 words)

  
 CHEMISTRY 102   (Site not responding. Last check: 2007-11-04)
You should be able to differentiate between the structures of primary, secondary and tertiary amines.
The tertiary structure of a protein refers to the coiling and bending of the helix.
Tertiary structure of proteins: the twisting, bending and coiling of the -helices due to ionic attractions, H-bonding.
virtual.parkland.edu /btreadway/102suplc.htm   (837 words)

  
 Psychiatric Drugs: Tertiary Amine Tricyclic Antidepressants
The tertiary tricyclic antidepressant amines, such as amitriptyline and imipramine, are demethylated to secondary amine metabolites, nortriptyline and desipramine, respectively.
The tertiary tricyclic amines have more side effects and greater lethality in overdose because of greater blockade of cholinergic, adrenergic and histaminic receptors compared to secondary amines.
Additionally, if a patient is sensitive to the sedative properties of medications, a secondary amine should be chosen over a tertiary amine.
psychiatric-drugs.org /2006/06/tertiary_amine_tricyclic_antid.html   (993 words)

  
 Transport of procainamide via H+/tertiary amine antiport system in rabbit intestinal brush-border membrane -- Katsura ...
Because transport of tertiary amines such as diphenhydramine and procainamide is pH dependent, the effect of an H
Recently, we (13) demonstrated that a pH-dependent tertiary amine transport system is present in human intestinal epithelial
In this context, the potency of tertiary amines to
ajpgi.physiology.org /cgi/content/full/279/4/G799   (3497 words)

  
 multiple nucleophilic substitution - halogenoalkanes and ammonia
The free amine will continue to be produced, and what was originally a reversible reaction becomes a one-way reaction - provided the free amine is removed by some other reaction as soon as it is formed.
That means that the primary amine is going to be a better nucleophile than ammonia is. You can therefore get a reaction between it and a molecule of the halogenoalkane.
It is tertiary because of the three alkyl groups attached to the nitrogen.
www.chemguide.co.uk /mechanisms/nucsub/amines.html   (985 words)

  
 Distinct Mechanisms of Block of Kv1.5 Channels by Tertiary and Quaternary Amine Clofilium Compounds -- Steidl and Yool ...
The quaternary ammonium compound clofilium and its tertiary amine derivative LY97241 were used to analyze mechanisms of block
Conversely, trapping of the tertiary amine lidocaine is less evident
The structures of clofilium and the tertiary ammonium analog LY97241 are shown in Fig.
www.biophysj.org /cgi/content/full/81/5/2606   (4704 words)

  
 Farrar, Grover Louis (1961-01-01) Part I: Cis- and trans-1,2-diaminocyclohexanes. Part II: A study of the tertiary ...
Part II: A study of the tertiary amine precursors of pirylene.
The observation of Sargent, Buchman and Farquhar, that the Hofmann degradation of N,N-dimethyl-[alpha]-bromomethylpyrrolidinium bromide does not give a single C7H13N amine, but a mixture of isomeric tertiary amines has been confirmed.
A probable course of formation of the C7H13N amine mixture from N,N-dimethyl-[alpha]-bromomethylpyrrolidinium bromide is discussed.
etd.caltech.edu /etd/available/etd-03282006-131742   (208 words)

  
 Medical Dictionary: Tertiary amine - WrongDiagnosis.com - WrongDiagnosis.com
Medical Dictionary: Tertiary amine - WrongDiagnosis.com - WrongDiagnosis.com
Tertiary amine : group of chemical compounds formed from ammonia by replacement of three of the hydrogen atoms by hydrocarbon radicals.
The term Tertiary amine can be used for:
www.wrongdiagnosis.com /medical/tertiary_amine_printer.htm   (152 words)

  
 P&G Chemicals : Your one stop oleochemicals shop
PandG produces tertiary (alkyl dimethyl) amines from olefin.
The olefin, typically of C12, C14, or C16 chain length, is brominated to form the alkyl bromide, which is then aminated with dimethylamine to form the tertiary amine (i.e., alkyl dimethylamine).
The tertiary amine contains one long chain (e.g., C12) and two short chains (methyl).
www.pgchemicals.com /default.asp?page=am&r=   (85 words)

  
 Chromatography :: View topic - Separation of Secondary Amine and Tertiary amine   (Site not responding. Last check: 2007-11-04)
But it's a nightmare fore the secondary amine...
Use 5% acetic acid to elute the secondary amine.
Acidic conditions protonate the silica gel, and the amine no longer binds by ion exchange.
www.sepsci.com /chromforum/viewtopic.php?p=13590   (393 words)

  
 D2074-92(1998) Standard Test Methods for Total, Primary, Secondary, and Tertiary Amine Values of Fatty Amines by ...
D2074-92(1998) Standard Test Methods for Total, Primary, Secondary, and Tertiary Amine Values of Fatty Amines by Alternative Indicator Method
1.1 These alternative test methods cover the indicator procedure for determining the total, primary, secondary, and tertiary amine values of fatty amines.
It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use>.
www.astm.org /DATABASE.CART/PAGES/D2074.htm   (144 words)

  
 [gmx-users] How can I define the nitrogen atom of the tertiary amine in force field?   (Site not responding. Last check: 2007-11-04)
[gmx-users] How can I define the nitrogen atom of the tertiary amine in force field?
Previous message: [gmx-users] How can I define the nitrogen atom of the tertiary amine in force field?
On Tue, 2004-09-14 at 16:49, Hanming wrote: > Dear All, > > There are a lot of tertiary amine in my molecule, that is, the nitrogen > atoms which are bonded to three methylene group.
www.gromacs.org /pipermail/gmx-users/2004-September/012270.html   (246 words)

  
 Bulletin of the Chemical Society of Ethiopia - Vol. 19, No. 2 (2005)
The magnetic shielding and its polarizabilities, have been calculated for tertiary butyl alcohol and tertiary butyl amine.
These have been used to rationalise the solvent shifts of the proton spectra of the interesting cosolvent systems with water recently measured by Kipkemboi, et al.
This site is maintained by NISC SA (National Inquiry Services Centre) as an initiative to support African-published journals.
www.ajol.info /viewarticle.php?id=23361   (200 words)

  
 Citebase - A Kinetic Scheme for Anhydride Curing of Diglycidyl Esterwith Tertiary Amine as Catalyst
A Kinetic Scheme for Anhydride Curing of Diglycidyl Esterwith Tertiary Amine as Catalyst
A kinetic model has been developed on the basis of reaction mechanisms proposed for the anhydride curing of diepoxides, using tertiary amine as catalyst.
The model has been tested for the cure reaction of a diglycidylester model compound, bis- (2,3-epoxypropyl) -1,3-ben-zenedicarboxylate, with hexahydrophthalic anhydride as the curing agent and benzyldi-methylamine as the catalyst, over the temperature range 10O-12O
citebase.eprints.org /cgi-bin/citations?id=oai:iiscePrints.OAI2:6101   (245 words)

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